Tomasz Olszewski – Department of Physical and Quantum Chemistry

Ph.D. D.Sc. Tomasz Olszewski

Associate Professor, Deputy Head of the Department of Physical and Quantum Chemistry

Wybrzeże Wyspiańskiego 27

PL-50370 Wrocław, Poland

tomasz.olszewski@pwr.edu.pl

(+48) 71 320 2917 or 3210

Office:Building A02, room 320a-b

Curriculum vitae

Bibliography

Files to download

Scentific interests

The main area of scientific interest is organic chemistry with particular emphasis on the synthesis of new organophosphorus compounds, having defined biological activity and/or interesting physical and chemical properties, as well as catalysis, in particular olefin metathesis and processes involving catalysts obtained from biomass derived from the phytoremediation of metal contaminated areas.

orcid
dona

Selected scientific articles

415588 JH9UWEZI 1 royal-society-of-chemistry-with-titles 50 date desc 1 title 965 https://huckel.pl/wp-content/plugins/zotpress/

Professional career

2019

Wroclaw University of Science and Technology — Associate Professor

Deputy Head of the Department of Physical and Quantum Chemistry

2013 - 2019

Wroclaw University of Science and Technology — Assistant Professor

2012 - 2013

Wroclaw University of Science and Technology — Research Assistant

Titles and degrees

2016

Wroclaw University of Science and Technology — Faculty of Chemistry – D.Sc. (habilitation) in chemical sciences (organic chemistry)

2006

Wroclaw University of Science and Technology — Faculty of Chemistry – Ph.D. in chemical sciences (organic chemistry)

2002

Wroclaw University of Science and Technology — Faculty of Chemistry – M.Sc. in chemistry (organic chemistry)

Scientific internships

2019 (5 days)

Centre National de la Recherche Scientifique — Montpellier, France – visiting professor

2018 (5 days)

Cardiff University — School of Chemistry, Cardiff, Wales, UK – visiting professor

2011 - 2012

Apeiron Synthesis S.A. — Wrocław – Project Manager

2008

University of Basque Country — Hiszpania – post-doctoral stay

2007 (12 months)

National Hellenic Research Foundation — Ateny, Grecja – post-doctoral stay, Marie-Curie scholarship

2002 (5 months)

University of Aarhus — Aarhus, Dania – scientific internship, Marie-Curie scholarship

2001 (5 months)

École National Supérieure de Chimie — Montpellier, Francja - scientific internship, ERASMUS

Awards

Awards of the Rector of the Wrocław University of Science and Technology for scientific activities and activities for the university (in 2015, 2016). Award of the Rector of Wrocław University of Technology for an outstanding doctoral dissertation (2006).

Other major awards and functions:

2019 – Member of the editorial board of “Organics” (MDPI);
2019 – travel scholarship of the National Agency for Academic Exchange;
since 2016 – board member of the Wrocław Branch of the Polish Chemical Society;
2012-2015 – laureate of the Iuventus Plus Ministry of Science and Higher Education program;
since 2006 – member of the Polish Chemical Society.

415588 624RWUWQ 1 royal-society-of-chemistry-with-titles 50 date desc year 1 title 965 https://huckel.pl/wp-content/plugins/zotpress/

%7B%22status%22%3A%22success%22%2C%22updateneeded%22%3Afalse%2C%22instance%22%3Afalse%2C%22meta%22%3A%7B%22request_last%22%3A50%2C%22request_next%22%3A50%2C%22used_cache%22%3Atrue%7D%2C%22data%22%3A%5B%7B%22key%22%3A%224UBLMQX6%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iwanejko%20et%20al.%22%2C%22parsedDate%22%3A%222020-04-08%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Iwanejko%2C%20M.%20Sowi%5Cu0144ski%2C%20E.%20Wojaczy%5Cu0144ska%2C%20T.%20K.%20Olszewski%20and%20M.%20G%5Cu00f3recki%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2020%5C%2Fra%5C%2Fd0ra02646h%26%23039%3B%26gt%3BAn%20approach%20to%20new%20chiral%20bicyclic%20imines%20and%20amines%20via%20Horner%5Cu2013Wadsworth%5Cu2013Emmons%20reaction%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BRSC%20Adv.%26lt%3B%5C%2Fi%26gt%3B%2C%202020%2C%20%26lt%3Bb%26gt%3B10%26lt%3B%5C%2Fb%26gt%3B%2C%2014618%5Cu201314629.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D4UBLMQX6%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22An%20approach%20to%20new%20chiral%20bicyclic%20imines%20and%20amines%20via%20Horner%5Cu2013Wadsworth%5Cu2013Emmons%20reaction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Jakub%22%2C%22lastName%22%3A%22Iwanejko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Mateusz%22%2C%22lastName%22%3A%22Sowi%5Cu0144ski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22El%5Cu017cbieta%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marcin%22%2C%22lastName%22%3A%22G%5Cu00f3recki%22%7D%5D%2C%22abstractNote%22%3A%22New%20chiral%20bicyclic%20imines%2C%20enamines%20and%20amines%20were%20prepared%20via%20Horner%5Cu2013Wadsworth%5Cu2013Emmons%20reaction%20of%20hexahydroquinoxalin-2%281H%29-one-derived%20phosphonate%2C%20as%20the%20source%20of%20a%20phosphonate%20carbanion%2C%20and%20a%20wide%20range%20of%20structurally%20diverse%20carbonyl%20substrates.%20The%20simplicity%20of%20the%20synthetic%20protocol%2C%20high%20selectivity%2C%20and%20broad%20substrate%20scope%20are%20the%20main%20advantages%20of%20the%20presented%20methodology.%22%2C%22date%22%3A%222020-04-08%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FD0RA02646H%22%2C%22ISSN%22%3A%222046-2069%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2020%5C%2Fra%5C%2Fd0ra02646h%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%22QLHX9TQJ%22%2C%22UL3NK4XX%22%2C%22782TAERM%22%5D%2C%22dateModified%22%3A%222020-06-09T13%3A39%3A29Z%22%7D%7D%2C%7B%22key%22%3A%22MM7RNVDT%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Bihanic%20et%20al.%22%2C%22parsedDate%22%3A%222020-03-19%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20Bihanic%2C%20K.%20Richards%2C%20T.%20K.%20Olszewski%20and%20C.%20Grison%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fchemistry-europe.onlinelibrary.wiley.com%5C%2Fdoi%5C%2Ffull%5C%2F10.1002%5C%2Fcctc.201901845%26%23039%3B%26gt%3BEco-Mn%20Ecocatalysts%3A%20Toolbox%20for%20Sustainable%20and%20Green%20Lewis%20Acid%20Catalysis%20and%20Oxidation%20Reactions%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BChemCatChem%26lt%3B%5C%2Fi%26gt%3B%2C%202020%2C%20%26lt%3Bb%26gt%3B12%26lt%3B%5C%2Fb%26gt%3B%2C%201529%5Cu20131545.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DMM7RNVDT%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Eco-Mn%20Ecocatalysts%3A%20Toolbox%20for%20Sustainable%20and%20Green%20Lewis%20Acid%20Catalysis%20and%20Oxidation%20Reactions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Camille%22%2C%22lastName%22%3A%22Bihanic%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Kenza%22%2C%22lastName%22%3A%22Richards%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Claude%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20Phytoextraction%20is%20one%20of%20the%20most%20promising%20phytotechnologies%20used%20to%20restore%20natural%20environments%20degraded%20by%20mining%20activities.%20In%20New%20Caledonia%2C%20a%20few%20plant%20species%2C%20which%20belong%20to%20the%20Grevillea%20genus%2C%20have%20the%20ability%20to%20extract%20Mn%20from%20soil%20and%20accumulate%20it%20in%20abundance%20%28over%201%3F%25%20of%20leaves%20dry%20weight%29.%20This%20review%20describes%20the%20use%20of%20Grevillea%20Mn-accumulating%20plant%20species%20to%20produce%20the%20first%20bio-sourced%20Mn%20catalysts%2C%20called%20Eco-Mn%20catalysts.%20Extensive%20structural%20studies%20of%20Eco-Mn%20catalysts%20have%20highlighted%20an%20original%20composition%20characteristic%20of%20their%20vegetal%20origin.%20Eco-Mn%20catalysts%20have%20demonstrated%20competitive%20catalytic%20activities%20compared%20to%20conventional%20Mn%20catalysts%20in%20Lewis%20acid%20catalysis%2C%20aminoreductions%2C%20alcohol%20oxidations%2C%20epoxidation%20reactions%2C%20oxidative%20cleavage%20of%201%2C2-diols%20and%20alkenes%20and%20%3FJanus%20catalysts%3F%20for%20sequential%20tandem%20oxidations%20such%20as%20tandem%20carbonyl-ene%20cyclisation%2C%20synthesis%20of%20substituted%20pyridines%20and%20oxidative%20iodination%20of%20ketones.%22%2C%22date%22%3A%22March%2019%2C%202020%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fcctc.201901845%22%2C%22ISSN%22%3A%221867-3880%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fchemistry-europe.onlinelibrary.wiley.com%5C%2Fdoi%5C%2Ffull%5C%2F10.1002%5C%2Fcctc.201901845%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%22QLHX9TQJ%22%2C%22JH9UWEZI%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A21%3A32Z%22%7D%7D%2C%7B%22key%22%3A%22R2DP4CHX%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222020-02-21%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20M.%20Bieniek%20and%20K.%20Skowerski%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.oprd.9b00483%26%23039%3B%26gt%3BRuthenium-Based%20Complexes%20Bearing%20Quaternary%20Ammonium%20Tags%20as%20Versatile%20Catalysts%20for%20Olefin%20Metathesis%3A%20From%20the%20Discovery%20to%20Practical%20Applications%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BOrg.%20Process%20Res.%20Dev.%26lt%3B%5C%2Fi%26gt%3B%2C%202020%2C%20%26lt%3Bb%26gt%3B24%26lt%3B%5C%2Fb%26gt%3B%2C%20125%5Cu2013145.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DR2DP4CHX%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ruthenium-Based%20Complexes%20Bearing%20Quaternary%20Ammonium%20Tags%20as%20Versatile%20Catalysts%20for%20Olefin%20Metathesis%3A%20From%20the%20Discovery%20to%20Practical%20Applications%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Micha%5Cu0142%22%2C%22lastName%22%3A%22Bieniek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krzysztof%22%2C%22lastName%22%3A%22Skowerski%22%7D%5D%2C%22abstractNote%22%3A%22This%20personal%20account%20describes%20the%20development%20and%20fine-tuning%20of%20pH-neutral%20quaternary-ammonium-tagged%20ruthenium-based%20complexes%2C%20their%20use%20as%20versatile%20catalysts%20for%20olefin%20metathesis%2C%20and%20the%20application%20of%20that%20transformation%20in%20the%20synthesis%20of%20complex%20molecules.%22%2C%22date%22%3A%222020-02-21%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facs.oprd.9b00483%22%2C%22ISSN%22%3A%221083-6160%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fdoi.org%5C%2F10.1021%5C%2Facs.oprd.9b00483%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%22QLHX9TQJ%22%2C%22JH9UWEZI%22%5D%2C%22dateModified%22%3A%222020-06-30T16%3A38%3A55Z%22%7D%7D%2C%7B%22key%22%3A%22TKTUI556%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Woli%5Cu0144ska%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Woli%26%23x144%3Bska%2C%20K.%20Ha%26%23x142%3Bdys%2C%20J.%20G%26%23xF3%3Bra%2C%20T.%20K.%20Olszewski%2C%20B.%20Boduszek%20and%20R.%20Latajka%2C%20Phosphonic%20and%20Phosphinic%20Acid%20Derivatives%20as%20Novel%20Tyrosinase%20Inhibitors%3A%20Kinetic%20Studies%20and%20Molecular%20Docking%2C%20%26lt%3Bi%26gt%3BChemistry%20and%20Biodiversity%26lt%3B%5C%2Fi%26gt%3B%2C%20%2C%20DOI%3A10.1002%5C%2Fcbdv.201900167.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DTKTUI556%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Phosphonic%20and%20Phosphinic%20Acid%20Derivatives%20as%20Novel%20Tyrosinase%20Inhibitors%3A%20Kinetic%20Studies%20and%20Molecular%20Docking%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Woli%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Ha%5Cu0142dys%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22G%5Cu00f3ra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Latajka%22%7D%5D%2C%22abstractNote%22%3A%22A%20dozen%20of%20phosphonic%20and%20phosphinic%20acid%20derivatives%20containing%20pyridine%20moiety%20were%20synthesized%20and%20its%20inhibitory%20activity%20toward%20mushroom%20tyrosinase%20was%20investigated.%20Moreover%2C%20molecular%20docking%20of%20these%20compounds%20to%20the%20active%20site%20of%20the%20enzyme%20was%20performed.%20All%20the%20compounds%20%281%5Cu201310%29%20demonstrated%20the%20inhibitory%20effect%20with%20the%20IC50%20and%20inhibition%20constants%20ranging%20millimolar%20concentrations.%20The%20obtained%20results%20indicate%20that%20the%20compounds%20show%20different%20types%20of%20inhibition%20%28competitive%2C%20noncompetitive%2C%20mixed%29%2C%20but%20all%20of%20them%20are%20reversible%20inhibitors.%20The%20obtained%20outcomes%20allowed%20to%20make%20the%20structure%5Cu2013activity%20relationship%20%28SAR%29%20analysis.%20Compound%204%20%28%5B%28benzylamino%29%28pyridin-2-yl%29methyl%5Dphenylphosphinic%20acid%29%20revealed%20the%20lowest%20IC50%20value%20of%200.3%20mm%20and%20inhibitory%20constant%20of%20Ki%200.076%20mm%2C%20with%20noncompetitive%20type%20and%20reversible%20mechanism%20of%20inhibition.%20According%20to%20SAR%20analysis%2C%20introducing%20bulky%20phenyl%20moieties%20to%20phosphonic%20and%20amino%20groups%20plays%20an%20important%20role%20in%20the%20inhibitory%20potency%20on%20activity%20of%20mushroom%20tyrosinase%20and%20could%20be%20useful%20in%20design%20and%20development%20of%20a%20new%20class%20of%20potent%20organophosphorus%20inhibitors%20of%20tyrosinase.%20Combined%20results%20of%20molecular%20docking%20and%20SAR%20analysis%20can%20be%20helpful%20in%20designing%20novel%20tyrosinase%20inhibitors%20of%20desired%20properties.%20They%20may%20have%20broad%20application%20in%20food%20industry%20and%20cosmetology.%20%5Cu00a9%202019%20Wiley-VHCA%20AG%2C%20Zurich%2C%20Switzerland%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fcbdv.201900167%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A22%3A31Z%22%7D%7D%2C%7B%22key%22%3A%22EZFC2VJ5%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Gu%5Cu0142ajski%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A5%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3B%26%23x141%3B.%20Gu%26%23x142%3Bajski%2C%20A.%20Tracz%2C%20K.%20Urbaniak%2C%20S.%20J.%20Czarnocki%2C%20M.%20Bieniek%20and%20T.%20K.%20Olszewski%2C%20Ammonium-tagged%20ruthenium-based%20catalysts%20for%20olefin%20metathesis%20in%20aqueous%20media%20under%20ultrasound%20and%20microwave%20irradiation%2C%20%26lt%3Bi%26gt%3BBeilstein%20Journal%20of%20Organic%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202019%2C%20%26lt%3Bb%26gt%3B15%26lt%3B%5C%2Fb%26gt%3B%2C%20160%26%23x2013%3B166.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DEZFC2VJ5%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ammonium-tagged%20ruthenium-based%20catalysts%20for%20olefin%20metathesis%20in%20aqueous%20media%20under%20ultrasound%20and%20microwave%20irradiation%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22%5Cu0141.%22%2C%22lastName%22%3A%22Gu%5Cu0142ajski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Tracz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Urbaniak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.J.%22%2C%22lastName%22%3A%22Czarnocki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Bieniek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22The%20influence%20of%20microwave%20and%20ultrasonic%20irradiation%20on%20the%20performance%20of%20ammonium-tagged%20Ru-based%20catalysts%20in%20olefin%20metathesis%20transformations%20in%20aqueous%20media%20was%20studied.%20Differences%20in%20the%20catalytic%20activity%20in%20correlation%20with%20the%20nature%20of%20the%20present%20counter%20ion%20and%20the%20size%20of%20the%20N-heterocyclic%20carbene%20%28NHC%29%20ligand%20were%20revealed.%20The%20presented%20methodology%20allows%20for%20preparation%20of%20a%20variety%20of%20polar%20and%20non-polar%20metathesis%20products%20under%20environmentally%20friendly%20conditions.%20%5Cu00a9%202019%20Gu%5Cu0142ajski%20et%20al.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.3762%5C%2Fbjoc.15.16%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A23%3A51Z%22%7D%7D%2C%7B%22key%22%3A%22D43FPYGJ%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iwanejko%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A5%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Iwanejko%2C%20A.%20Brol%2C%20B.%20M.%20Szyja%2C%20M.%20Daszkiewicz%2C%20E.%20Wojaczy%26%23x144%3Bska%20and%20T.%20K.%20Olszewski%2C%20Aminophosphonates%20and%20aminophosphonic%20acids%20with%20tetrasubstituted%20stereogenic%20center%3A%20Diastereoselective%20synthesis%20from%20cyclic%20ketimines%2C%20%26lt%3Bi%26gt%3BOrganic%20and%20Biomolecular%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202019%2C%20%26lt%3Bb%26gt%3B17%26lt%3B%5C%2Fb%26gt%3B%2C%207352%26%23x2013%3B7359.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DD43FPYGJ%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Aminophosphonates%20and%20aminophosphonic%20acids%20with%20tetrasubstituted%20stereogenic%20center%3A%20Diastereoselective%20synthesis%20from%20cyclic%20ketimines%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Iwanejko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Brol%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.M.%22%2C%22lastName%22%3A%22Szyja%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Daszkiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22New%20chiral%20tetrasubstituted%20aminophosphonic%20acid%20derivatives%20of%20hexahydroquinoxalin-2%281H%29-one%20were%20synthesised%20via%20highly%20diastereoselective%20hydrophosphonylation%20of%20the%20corresponding%20imines%20with%20tris%28trimethylsilyl%29%20phosphite%20as%20phosphorus%20nucleophile.%20High%20asymmetric%20induction%2C%20good%20yields%2C%20mild%20reaction%20conditions%2C%20and%20ease%20of%20purification%20of%20the%20final%20products%20are%20the%20key%20advantages%20of%20the%20presented%20protocol.%20%5Cu00a9%202019%20The%20Royal%20Society%20of%20Chemistry.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fc9ob01346f%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%2C%22JH9UWEZI%22%2C%22UL3NK4XX%22%5D%2C%22dateModified%22%3A%222020-06-07T11%3A22%3A09Z%22%7D%7D%2C%7B%22key%22%3A%22NZAK3D3B%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A5%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20P.%20Adler%20and%20C.%20Grison%2C%20Bio-based%20catalysts%20from%20biomass%20issued%20after%20decontamination%20of%20effluents%20rich%20in%20copper%26%23x2014%3B%20an%20innovative%20approach%20towards%20greener%20copper-based%20catalysis%2C%20%26lt%3Bi%26gt%3BCatalysts%26lt%3B%5C%2Fi%26gt%3B%2C%20%2C%20DOI%3A10.3390%5C%2Fcatal9030214.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DNZAK3D3B%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Bio-based%20catalysts%20from%20biomass%20issued%20after%20decontamination%20of%20effluents%20rich%20in%20copper%5Cu2014%20an%20innovative%20approach%20towards%20greener%20copper-based%20catalysis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Adler%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22The%20abundance%20of%20Cu-contaminated%20effluents%20and%20the%20serious%20risk%20of%20contamination%20of%20the%20aquatic%20systems%20combine%20to%20provide%20strong%20motivating%20factors%20to%20tackle%20this%20environmental%20problem.%20The%20treatment%20of%20polluted%20effluents%20by%20rhizofiltration%20and%20biosorption%20is%20an%20interesting%20ecological%20alternative.%20Taking%20advantage%20of%20the%20remarkable%20ability%20of%20the%20selected%20plants%20to%20bioconcentrate%20copper%20into%20roots%2C%20these%20methods%20have%20been%20exploited%20for%20the%20decontamination%20of%20copper-rich%20effluents.%20Herein%2C%20we%20present%20an%20overview%20on%20the%20utility%20of%20the%20resulted%20copper-rich%20biomass%20for%20the%20preparation%20of%20novel%20bio-sourced%20copper-based%20catalysts%20for%20copper-mediated%20reactions%3A%20from%20the%20bioaccumulation%20of%20copper%20in%20plant%2C%20to%20the%20preparation%20and%20full%20analysis%20of%20the%20new%20Eco-Cu%20catalysts%2C%20and%20their%20application%20in%20selected%20key%20reactions.%20The%20hydrolysis%20of%20a%20thiophosphate%2C%20an%20Ullmann-type%20coupling%20leading%20to%20N-and%20O-arylated%20compounds%2C%20and%20a%20CuAAC%20%5Cu201cclick%5Cu201d%20reaction%2C%20all%20performed%20under%20green%20and%20environmentally%20friendly%20conditions%2C%20will%20be%20described.%20%5Cu00a9%202019%20by%20the%20authors.%20Licensee%20MDPI%2C%20Basel%2C%20Switzerland.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.3390%5C%2Fcatal9030214%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%2C%22JH9UWEZI%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A23%3A07Z%22%7D%7D%2C%7B%22key%22%3A%229UIARGTE%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iwanejko%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A5%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Iwanejko%2C%20A.%20Brol%2C%20B.%20Szyja%2C%20M.%20Daszkiewicz%2C%20E.%20Wojaczy%26%23x144%3Bska%20and%20T.%20K.%20Olszewski%2C%20Hydrophosphonylation%20of%20chiral%20hexahydroquinoxalin-2%281H%29-one%20derivatives%20as%20an%20effective%20route%20to%20new%20bicyclic%20compounds%3A%20Aminophosphonates%2C%20enamines%20and%20imines%2C%20%26lt%3Bi%26gt%3BTetrahedron%26lt%3B%5C%2Fi%26gt%3B%2C%202019%2C%20%26lt%3Bb%26gt%3B75%26lt%3B%5C%2Fb%26gt%3B%2C%201431%26%23x2013%3B1439.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D9UIARGTE%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Hydrophosphonylation%20of%20chiral%20hexahydroquinoxalin-2%281H%29-one%20derivatives%20as%20an%20effective%20route%20to%20new%20bicyclic%20compounds%3A%20Aminophosphonates%2C%20enamines%20and%20imines%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Iwanejko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Brol%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Szyja%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Daszkiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22A%20series%20of%20new%20aminophosphonate%20and%20phosphonic%20acid%20derivatives%20of%20hexahydroquinoxalin-2%281H%29-ones%20and%20tetrahydroquinoxalin-2%281H%29-ones%20were%20synthesised%20via%20hydrophosphonylation%20of%20the%20corresponding%20bicyclic%20imines%20with%20various%20dialkyl%20or%20diaryl%20H-phosphonates%2C%20H-phosphinates%20or%20H-phosphine%20oxides%20as%20phosphorus%20nucleophiles.%20The%20utility%20of%20the%20obtained%20compounds%20was%20demonstrated%20by%20their%20application%20as%20a%20source%20of%20phosphonate%20carbanion%20in%20the%20Horner-Wadsworth-Emmons%20%28HWE%29%20reaction%20leading%20to%20new%20bicyclic%20amines%20with%20an%20exocyclic%2C%20and%20unexpectedly%2C%20also%20endocyclic%20double%20bond%20depending%20on%20the%20structure%20of%20the%20aldehyde%20used.%20%5Cu00a9%202019%20Elsevier%20Ltd%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tet.2019.01.062%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%2C%22UL3NK4XX%22%5D%2C%22dateModified%22%3A%222020-06-07T11%3A22%3A24Z%22%7D%7D%2C%7B%22key%22%3A%22624HAU6V%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Stanovych%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BA.%20Stanovych%2C%20M.%20Balloy%2C%20T.%20K.%20Olszewski%2C%20E.%20Petit%20and%20C.%20Grison%2C%20Depollution%20of%20mining%20effluents%3A%20innovative%20mobilization%20of%20plant%20resources%2C%20%26lt%3Bi%26gt%3BEnvironmental%20Science%20and%20Pollution%20Research%26lt%3B%5C%2Fi%26gt%3B%2C%202019%2C%20%26lt%3Bb%26gt%3B26%26lt%3B%5C%2Fb%26gt%3B%2C%2019327%26%23x2013%3B19334.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D624HAU6V%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Depollution%20of%20mining%20effluents%3A%20innovative%20mobilization%20of%20plant%20resources%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Stanovych%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Balloy%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Petit%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22Based%20on%20the%20ability%20of%20some%20specific%20aquatic%20plants%20to%20concentrate%20metals%20in%20their%20roots%2C%20we%20propose%20an%20innovative%20biosorption%20system%20to%20clean%20up%20mining%20effluents.%20The%20system%20we%20propose%20represents%20an%20interesting%20solution%20to%20an%20important%20environmental%20problem%2C%20the%20decontamination%20of%20metal-polluted%20water%20and%20prevention%20of%20dispersal%20of%20metals%20into%20the%20environment.%20The%20solution%20presented%20is%20a%20form%20of%20ecological%20recycling%20of%20Zn%2C%20an%20essential%20primary%20metal%20in%20many%20industrial%20applications.%20Finally%2C%20the%20methodology%20developed%20is%20a%20sustainable%20way%20of%20managing%20the%20biomass%20from%20eradication%20or%20control%20of%20invasive%20plants.%20%5Cu00a9%202019%2C%20Springer-Verlag%20GmbH%20Germany%2C%20part%20of%20Springer%20Nature.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1007%5C%2Fs11356-019-05027-y%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A22%3A53Z%22%7D%7D%2C%7B%22key%22%3A%2287CAL5U4%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22De%20Laet%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20De%20Laet%2C%20T.%20K.%20Olszewski%20and%20C.%20Grison%2C%20Melliferous%20potential%20of%20Mentha%20aquatica%2C%20%26lt%3Bi%26gt%3BJournal%20of%20Apicultural%20Research%26lt%3B%5C%2Fi%26gt%3B%2C%202019%2C%20%26lt%3Bb%26gt%3B58%26lt%3B%5C%2Fb%26gt%3B%2C%20714%26%23x2013%3B719.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D87CAL5U4%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Melliferous%20potential%20of%20Mentha%20aquatica%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22De%20Laet%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22The%20abundance%20and%20diversity%20of%20flowers%20have%20declined%20and%20bees%20are%20chronically%20exposed%20to%20numerous%20pressures%20such%20as%20cocktails%20of%20agrochemicals%2C%20parasites%20and%20predators%2C%20climate%20change%2C%20and%20lack%20of%20floral%20resources.%20Chronic%20exposure%20to%20multiple%20interacting%20stressors%20is%20driving%20honey%20bee%20colony%20losses%20and%20declines%20of%20wild%20pollinators%2C%20that%20may%20lead%20to%20%5Cu201cpollination%20crisis%5Cu201d%20in%20which%20crop%20yields%20begin%20to%20fall.%20Effective%20monitoring%20of%20pollinator%20populations%20is%20urgently%20needed%20to%20inform%20management%20strategies%20into%20the%20future.%20Additionally%2C%20strategies%20to%20reinforce%20the%20health%20and%20well-being%20of%20bees%20are%20needed.%20Based%20on%20the%20literature%20data%20gathered%2C%20we%20propose%20to%20use%20Mentha%20aquatica%20as%20an%20additional%20melliferous%20plant%20to%20support%20bees%5Cu2019%20nutritional%20needs%20and%20develop%20diverse%20and%20nutritionally%20balanced%20plant%20communities.%20Here%2C%20we%20review%20the%20literature%20data%20concerning%20the%20implantation%20of%20the%20genus%20Mentha%20to%20complete%20the%20foraging%20schedule%20of%20Apis%20mellifera%20with%20special%20emphasis%20on%20its%20use%20as%20valuable%20nutritionally%20resource%20and%20source%20of%20nutritional%20diversity.%20Additionally%2C%20we%20discuss%20the%20aspects%20of%20attractiveness%20of%20genus%20Mentha%20to%20honey%20bees.%20Our%20list%20of%20facts%20thus%20far%20reported%20in%20the%20literature%20on%20the%20use%20of%20M.%20aquatica%20will%20help%20in%20implementation%20of%20this%20specimen%20in%20helping%20the%20bees%20that%20are%20in%20difficult%20situation.%20%5Cu00a9%202019%2C%20%5Cu00a9%202019%20International%20Bee%20Research%20Association.%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1080%5C%2F00218839.2019.1656160%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A23%3A59Z%22%7D%7D%2C%7B%22key%22%3A%22IM45L5W4%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22%5Cu017byma%5Cu0144czyk-Duda%20et%20al.%22%2C%22parsedDate%22%3A%222019%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20%5Cu017byma%5Cu0144czyk-Duda%2C%20N.%20Dunal%2C%20M.%20Brzezi%5Cu0144ska-Rodak%2C%20A.%20Osiewa%5Cu0142a%2C%20T.%20K.%20Olszewski%2C%20M.%20Klimek-Ochab%20and%20M.%20A.%20Serafin-Lewa%5Cu0144czuk%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0045206818313270%3Fvia%253Dihub%26%23039%3B%26gt%3BFirst%20biological%20conversion%20of%20chiral%20heterophosphonate%20derivative%20-%20scaling%20and%20paths%20of%20conversion%20discussion%20%5C%2F%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BBioorganic%20Chemistry.%26lt%3B%5C%2Fi%26gt%3B%2C%20%2C%20DOI%3A10.1016%5C%2Fj.bioorg.2019.01.047.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DIM45L5W4%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22First%20biological%20conversion%20of%20chiral%20heterophosphonate%20derivative%20-%20scaling%20and%20paths%20of%20conversion%20discussion%20%5C%2F%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ewa%22%2C%22lastName%22%3A%22%5Cu017byma%5Cu0144czyk-Duda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Natalia%22%2C%22lastName%22%3A%22Dunal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ma%5Cu0142gorzata%22%2C%22lastName%22%3A%22Brzezi%5Cu0144ska-Rodak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Angelika%22%2C%22lastName%22%3A%22Osiewa%5Cu0142a%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Magdalena%22%2C%22lastName%22%3A%22Klimek-Ochab%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Monika%20A.%22%2C%22lastName%22%3A%22Serafin-Lewa%5Cu0144czuk%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222019%22%2C%22language%22%3A%22eng%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.bioorg.2019.01.047%22%2C%22ISSN%22%3A%220045-2068%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fwww.sciencedirect.com%5C%2Fscience%5C%2Farticle%5C%2Fpii%5C%2FS0045206818313270%3Fvia%253Dihub%22%2C%22collections%22%3A%5B%22K9CGVAY6%22%2C%22624RWUWQ%22%2C%22JH9UWEZI%22%5D%2C%22dateModified%22%3A%222020-06-02T13%3A29%3A12Z%22%7D%7D%2C%7B%22key%22%3A%22GDF3D33X%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Tracz%20et%20al.%22%2C%22parsedDate%22%3A%222018-05-29%22%2C%22numChildren%22%3A6%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BA.%20Tracz%2C%20A.%20Gawin%2C%20M.%20Bieniek%2C%20T.%20K.%20Olszewski%20and%20K.%20Skowerski%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttps%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2018%5C%2Fnj%5C%2Fc8nj00614h%26%23039%3B%26gt%3BAmmonium%20NHC-tagged%20olefin%20metathesis%20catalysts%20%5Cu2013%20influence%20of%20counter-ions%20on%20catalytic%20activity%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BNew%20J.%20Chem.%26lt%3B%5C%2Fi%26gt%3B%2C%202018%2C%20%26lt%3Bb%26gt%3B42%26lt%3B%5C%2Fb%26gt%3B%2C%208609%5Cu20138614.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DGDF3D33X%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ammonium%20NHC-tagged%20olefin%20metathesis%20catalysts%20%5Cu2013%20influence%20of%20counter-ions%20on%20catalytic%20activity%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Andrzej%22%2C%22lastName%22%3A%22Tracz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Anna%22%2C%22lastName%22%3A%22Gawin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Micha%5Cu0142%22%2C%22lastName%22%3A%22Bieniek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krzysztof%22%2C%22lastName%22%3A%22Skowerski%22%7D%5D%2C%22abstractNote%22%3A%22Ruthenium-based%20catalysts%20bearing%20quaternary%20ammonium%20groups%20in%20their%20N-heterocyclic%20carbene%20%28NHC%29%20fragments%20and%20different%20counter-ions%20were%20synthesised%20and%20tested%20in%20various%20olefin%20metathesis%20transformations.%20Differences%20in%20catalytic%20activity%20in%20correlation%20with%20the%20nature%20of%20the%20present%20counter-ion%20were%20revealed.%20The%20unique%20properties%20of%20the%20described%20catalysts%20allow%20for%20the%20effective%20preparation%20of%20a%20variety%20of%20metathesis%20products%20with%20low%20ruthenium%20contamination%20and%20under%20green%20chemistry%20conditions.%22%2C%22date%22%3A%222018-05-29%22%2C%22language%22%3A%22en%22%2C%22DOI%22%3A%2210.1039%5C%2FC8NJ00614H%22%2C%22ISSN%22%3A%221369-9261%22%2C%22url%22%3A%22https%3A%5C%2F%5C%2Fpubs.rsc.org%5C%2Fen%5C%2Fcontent%5C%2Farticlelanding%5C%2F2018%5C%2Fnj%5C%2Fc8nj00614h%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%228FEGW2TQ%22%2C%22JH9UWEZI%22%5D%2C%22dateModified%22%3A%222020-06-09T13%3A46%3A58Z%22%7D%7D%2C%7B%22key%22%3A%22PZ46L5KK%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Iwanejko%20et%20al.%22%2C%22parsedDate%22%3A%222018%22%2C%22numChildren%22%3A5%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Iwanejko%2C%20E.%20Wojaczy%26%23x144%3Bska%20and%20T.%20K.%20Olszewski%2C%20Green%20chemistry%20and%20catalysis%20in%20Mannich%20reaction%2C%20%26lt%3Bi%26gt%3BCurrent%20Opinion%20in%20Green%20and%20Sustainable%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202018%2C%20%26lt%3Bb%26gt%3B10%26lt%3B%5C%2Fb%26gt%3B%2C%2027%26%23x2013%3B34.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DPZ46L5KK%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Green%20chemistry%20and%20catalysis%20in%20Mannich%20reaction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Iwanejko%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22In%20the%20search%20for%20high%20yielding%2C%20sustainable%20and%20green%20transformations%20leading%20to%20desired%20products%20with%20high%20level%20of%20structural%20complexity%20and%20desired%20functionality%2C%20the%20multicomponent%20reactions%20appear%20as%20very%20promising%20alternative.%20Mannich%20reaction%20is%20an%20excellent%20example%20of%20multicomponent%20processes%20that%20enables%20formation%20of%20new%20carbon%5Cu2013carbon%20bonds%20leading%20to%20%5Cu03b2-amino%20carbonyl%20compounds%20and%201%2C2-amino%20alcohol%20derivatives.%20The%20latter%20are%20pivotal%20building%20blocks%20used%20in%20the%20preparation%20of%20biologically%20active%20compounds%2C%20versatile%20synthetic%20intermediates%2C%20and%20natural%20products.%20The%20ability%20to%20carry%20out%20this%20transformation%20in%20water%20makes%20it%20even%20more%20attractive%20and%20no%20wonder%20that%20this%20fact%20has%20gained%20significant%20attention%20of%20chemical%20society.%20In%20this%20review%2C%20we%20critically%20discuss%20the%20most%20prominent%20examples%20of%20catalytic%20Mannich%20reaction%20performed%20in%20water%20developed%20over%20the%20past%2010%20years.%20%5Cu00a9%202018%20Elsevier%20B.V.%22%2C%22date%22%3A%222018%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.cogsc.2018.02.006%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%228FEGW2TQ%22%2C%22UL3NK4XX%22%5D%2C%22dateModified%22%3A%222020-06-07T11%3A22%3A30Z%22%7D%7D%2C%7B%22key%22%3A%22VB6Z4LWV%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Kmiecik%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BN.%20Kmiecik%2C%20M.%20Serafin%2C%20E.%20Zymanczyk-Duda%20and%20T.%20K.%20Olszewski%2C%20Rapid%20enantiodifferentation%20of%20chiral%20organophosphorus%20compounds%20by%2031P%20NMR%20spectroscopy%20in%20the%20presence%20of%20%26%23x3B1%3Bcyclodextrin%20as%20the%20chiral%20solvating%20agent%2C%20%26lt%3Bi%26gt%3BSpectroscopy%20%28Santa%20Monica%29%26lt%3B%5C%2Fi%26gt%3B%2C%202017%2C%20%26lt%3Bb%26gt%3B32%26lt%3B%5C%2Fb%26gt%3B%2C%2036%26%23x2013%3B39%20and%2049.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DVB6Z4LWV%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Rapid%20enantiodifferentation%20of%20chiral%20organophosphorus%20compounds%20by%2031P%20NMR%20spectroscopy%20in%20the%20presence%20of%20%5Cu03b1cyclodextrin%20as%20the%20chiral%20solvating%20agent%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22N.%22%2C%22lastName%22%3A%22Kmiecik%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Serafin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Zymanczyk-Duda%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A23Z%22%7D%7D%2C%7B%22key%22%3A%22SX46QWWY%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Czarnocki%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BS.%20J.%20Czarnocki%2C%20I.%20Czelu%26%23x15B%3Bniak%2C%20T.%20K.%20Olszewski%2C%20M.%20Malinska%2C%20K.%20Wo%26%23x17A%3Bniak%20and%20K.%20Grela%2C%20Rational%20and%20Then%20Serendipitous%20Formation%20of%20Aza%20Analogues%20of%20Hoveyda-Type%20Catalysts%20Containing%20a%20Chelating%20Ester%20Group%20Leading%20to%20a%20Polymerization%20Catalyst%20Family%2C%20%26lt%3Bi%26gt%3BACS%20Catalysis%26lt%3B%5C%2Fi%26gt%3B%2C%202017%2C%20%26lt%3Bb%26gt%3B7%26lt%3B%5C%2Fb%26gt%3B%2C%204115%26%23x2013%3B4121.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DSX46QWWY%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Rational%20and%20Then%20Serendipitous%20Formation%20of%20Aza%20Analogues%20of%20Hoveyda-Type%20Catalysts%20Containing%20a%20Chelating%20Ester%20Group%20Leading%20to%20a%20Polymerization%20Catalyst%20Family%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.J.%22%2C%22lastName%22%3A%22Czarnocki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22I.%22%2C%22lastName%22%3A%22Czelu%5Cu015bniak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Malinska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Wo%5Cu017aniak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Grela%22%7D%5D%2C%22abstractNote%22%3A%22Analogues%20of%20the%20well-known%20Hoveyda-Grubbs%20catalyst%20bearing%20both%20a%20chelating%20ester%20function%20and%20a%20chelating%20nitrogen%20atom%20were%20obtained.%20These%20complexes%20behave%20differently%20depending%20on%20the%20character%20of%20the%20chelating%20amine.%20Complexes%20containing%20a%20secondary%20amine%20underwent%20unexpected%20spontaneous%20oxidation%20of%20the%20amine%20group%2C%20leading%20to%20the%20Schiff%20base%20analogues.%20In%20contrast%2C%20complexes%20containing%20a%20tertiary%20amine%20were%20prone%20to%20intramolecular%20cyclization%20in%20the%20presence%20of%20a%20base%20%28Et3N%29.%20Probing%20the%20activity%20of%20such%20%28pre%29catalysts%20in%20ring-closing%20metathesis%20reactions%20%28RCMs%29%20revealed%20their%20dormant%20character%20and%20excellent%20thermo-switchability.%20In%20particular%2C%20complexes%20bearing%20an%20iminium%20nitrogen%20fragment%20were%20found%20to%20be%20very%20useful%20in%20a%20delayed%20ring-opening%20metathesis%20polymerization%20%28ROMP%29%20and%20were%20therefore%20commercialized.%20%5Cu00a9%202017%20American%20Chemical%20Society.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Facscatal.7b00843%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A28Z%22%7D%7D%2C%7B%22key%22%3A%22XJ4R2N9W%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Proniewicz%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Proniewicz%2C%20S.%20Vantasin%2C%20T.%20K.%20Olszewski%2C%20B.%20Boduszek%20and%20Y.%20Ozaki%2C%20Biological%20application%20of%20water-based%20electrochemically%20synthesized%20CuO%20leaf-like%20arrays%3A%20SERS%20response%20modulated%20by%20the%20positional%20isomerism%20and%20interface%20type%2C%20%26lt%3Bi%26gt%3BPhysical%20Chemistry%20Chemical%20Physics%26lt%3B%5C%2Fi%26gt%3B%2C%202017%2C%20%26lt%3Bb%26gt%3B19%26lt%3B%5C%2Fb%26gt%3B%2C%2031842%26%23x2013%3B31855.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DXJ4R2N9W%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Biological%20application%20of%20water-based%20electrochemically%20synthesized%20CuO%20leaf-like%20arrays%3A%20SERS%20response%20modulated%20by%20the%20positional%20isomerism%20and%20interface%20type%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22S.%22%2C%22lastName%22%3A%22Vantasin%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Ozaki%22%7D%5D%2C%22abstractNote%22%3A%22Cupric%20oxide%20leaf-like%20nanostructures%20%28CuONSs%29%20%28average%20dimensions%3A%2080-180%20nm%20in%20width%20and%20400-750%20nm%20in%20length%29%20were%20synthesized%20via%20anodic%20electrochemical%20dissolution%20of%20copper%20in%20an%20ethanol%20solution%20containing%20LiCl%20electrolyte%20and%20water.%20Ultraviolet-visible%20%28UV-Vis%29%2C%20Fourier-transform%20infrared%20%28FT-IR%29%2C%20and%20Raman%20spectroscopies%20as%20well%20as%20scanning%20electron%20microscope%20%28SEM%29%2C%20high-resolution%20transmission%20electron%20microscopy%20with%20energy%20dispersive%20X-ray%20%28HD-TEM-EDS%29%2C%20X-ray%20photoelectron%20spectroscopy%20%28XPS%29%2C%20and%20X-ray%20powder%20diffraction%20%28XRD%29%20were%20used%20to%20explore%20the%20metal%20surface%20plasmon%2C%20size%2C%20rheology%2C%20and%20structure%20of%20CuONSs.%20Then%2C%20pyridine%20%5Cu03b1-aminophosphinic%20acid%20isomers%20%28%5Cu03b1-%2C%20%5Cu03b2-%2C%20and%20%5Cu03b3-NHPy%29%20were%20synthesized%20and%20assembled%20on%20the%20CuONS%5C%2Fair%20and%20CuONS%5C%2Faqueous%20solution%20interfaces%20at%20the%20pH%20level%20of%20solution%20%3D%207.%20Differences%20in%20adsorption%20and%20thus%20in%20the%20spectral%20response%20resulting%20from%20positional%20isomerism%20were%20examined%20by%20surface-enhanced%20Raman%20scattering%20%28SERS%29%20with%20an%20excitation%20wavelength%20of%20785%20nm.%20The%20manner%20of%20interaction%20of%20the%20investigated%20isomers%20with%20CuONSs%20in%20an%20aqueous%20solution%20was%20discussed%20in%20detail%20and%20compared%20with%20that%20at%20the%20CuONS%5C%2Fair%20interface.%20For%20%5Cu03b3-NHPy%2C%20at%20the%20CuONS%5C%2Fwater%20interface%2C%20the%20time-dependent%20changes%20in%20the%20spectral%20profile%20were%20observed%20and%20analyzed.%20For%20%5Cu03b2-NHPy%20at%20the%20CuONS%5C%2Fair%20interface%2C%20tip-enhanced%20Raman%20scattering%20%28TERS%29%20measurements%20were%20performed.%20These%20measurements%20allowed%20observing%20single%20molecule%20behavior%20and%20avoiding%20interference%20from%20the%20molecule%26%23039%3Bs%20surrounding%20environment.%20%5Cu00a9%202017%20the%20Owner%20Societies.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fc7cp06001g%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A13Z%22%7D%7D%2C%7B%22key%22%3A%22YRRTFT46%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Proniewicz%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Proniewicz%2C%20B.%20Gralec%2C%20T.%20K.%20Olszewski%20and%20B.%20Boduszek%2C%20Aqueous%20platinum%20nanoparticles%20solution%20for%20the%20detection%20of%20pyridine%20derivatives%20of%20aminophosphinic%20acid.%20Influence%20of%20positional%20isomerism%2C%20%26lt%3Bi%26gt%3BApplied%20Surface%20Science%26lt%3B%5C%2Fi%26gt%3B%2C%202017%2C%20%26lt%3Bb%26gt%3B425%26lt%3B%5C%2Fb%26gt%3B%2C%20941%26%23x2013%3B947.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DYRRTFT46%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Aqueous%20platinum%20nanoparticles%20solution%20for%20the%20detection%20of%20pyridine%20derivatives%20of%20aminophosphinic%20acid.%20Influence%20of%20positional%20isomerism%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Gralec%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%5D%2C%22abstractNote%22%3A%22Unsupported%20platinum%20nanoparticles%20%28PtNPs%29%20%28%5Cu223c12%5Cu00a0nm%20in%20diameter%29%20were%20synthetized%20by%20the%20polyol%20method%20and%20ultraviolet-visible%20spectroscopy%20%28UV%5Cu2013vis%29%2C%20scanning%20electron%20microscope%20%28SEM%29%2C%20and%20X-ray%20powder%20diffraction%20%28XRD%29%20characteristic%20of%20their%20agglomerates%20were%20examined.%20Then%2C%20three%20pyridine%20%5Cu03b1%5Cu2212aminophosphinic%20acid%20isomers%20%28%5Cu03b1%5Cu2013%2C%20%5Cu03b2%5Cu2013%2C%20and%20%5Cu03b3%5Cu2013%29%20were%20synthetized%20and%20assembled%20on%20the%20surface%20of%20PtNPs.%20Differences%20in%20adsorption%20and%20thus%2C%20in%20the%20spectral%20response%20resulting%20from%20positional%20isomerism%2C%20were%20checked%20by%20surface-enhanced%20Raman%20scattering%20%28SERS%29%20at%20785%5Cu00a0nm%20excitation%20wavelength.%20The%20manner%20of%20interaction%20of%20the%20investigated%20isomers%20with%20PtNPs%20were%20discussed%20and%20compared.%20General%20conclusions%20were%20drowned.%20%5Cu00a9%202017%20Elsevier%20B.V.%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apsusc.2017.07.110%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A18Z%22%7D%7D%2C%7B%22key%22%3A%227N6EB4HM%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Dunal%20et%20al.%22%2C%22parsedDate%22%3A%222017%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BN.%20Dunal%2C%20M.%20A.%20Serafin-Lewa%5Cu0144czuk%2C%20T.%20K.%20Olszewski%20and%20E.%20%5Cu017byma%5Cu0144czyk-Duda%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttp%3A%5C%2F%5C%2Fwww.spectroscopyonline.com%5C%2Frapid-enantiodifferentation-chiral-organophosphorus-compounds-31p-nmr-spectroscopy-presence-cyclodex%26%23039%3B%26gt%3BRapid%20enantiodifferentation%20of%20chiral%20organophosphorus%20compounds%20by%2031P%20NMR%20spectroscopy%20in%20the%20presence%20of%20%5Cu03b1-cyclodextrin%20as%20the%20chiral%20solvating%20agent%20%5C%2F%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BSpectroscopy.%26lt%3B%5C%2Fi%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D7N6EB4HM%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Rapid%20enantiodifferentation%20of%20chiral%20organophosphorus%20compounds%20by%2031P%20NMR%20spectroscopy%20in%20the%20presence%20of%20%5Cu03b1-cyclodextrin%20as%20the%20chiral%20solvating%20agent%20%5C%2F%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Natalia%22%2C%22lastName%22%3A%22Dunal%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Monika%20A.%22%2C%22lastName%22%3A%22Serafin-Lewa%5Cu0144czuk%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ewa%22%2C%22lastName%22%3A%22%5Cu017byma%5Cu0144czyk-Duda%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222017%22%2C%22language%22%3A%22eng%22%2C%22DOI%22%3A%22%22%2C%22ISSN%22%3A%220887-6703%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fwww.spectroscopyonline.com%5C%2Frapid-enantiodifferentation-chiral-organophosphorus-compounds-31p-nmr-spectroscopy-presence-cyclodex%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-02T13%3A29%3A14Z%22%7D%7D%2C%7B%22key%22%3A%22QT9QT55M%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Clav%5Cu00e9%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BG.%20Clav%26%23xE9%3B%2C%20C.%20Garel%2C%20C.%20Poullain%2C%20B.-L.%20Renard%2C%20T.%20K.%20Olszewski%2C%20B.%20Lange%2C%20M.%20Shutcha%2C%20M.-P.%20Faucon%20and%20C.%20Grison%2C%20Ullmann%20reaction%20through%20ecocatalysis%3A%20Insights%20from%20bioresource%20and%20synthetic%20potential%2C%20%26lt%3Bi%26gt%3BRSC%20Advances%26lt%3B%5C%2Fi%26gt%3B%2C%202016%2C%20%26lt%3Bb%26gt%3B6%26lt%3B%5C%2Fb%26gt%3B%2C%2059550%26%23x2013%3B59564.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DQT9QT55M%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Ullmann%20reaction%20through%20ecocatalysis%3A%20Insights%20from%20bioresource%20and%20synthetic%20potential%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22G.%22%2C%22lastName%22%3A%22Clav%5Cu00e9%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Garel%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Poullain%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.-L.%22%2C%22lastName%22%3A%22Renard%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Lange%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Shutcha%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.-P.%22%2C%22lastName%22%3A%22Faucon%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22We%20report%20the%20elaboration%20of%20novel%20bio-sourced%20ecocatalysts%20for%20the%20Ullmann%20coupling%20reaction.%20Ecocatalysis%20is%20based%20on%20the%20recycling%20of%20metals%20issued%20from%20phytoremediation%20or%20rehabilitation%2C%20and%20an%20innovative%20chemical%20valorization%20of%20the%20subsequent%20biomass%20in%20the%20field%20of%20catalysis.%20Here%2C%20we%20describe%20efficient%20copper%20accumulation%20by%20plants%20via%20phytoextraction%20and%20rhizofiltration.%20These%20phytotechnologies%20were%20revisited%20to%20demonstrate%20a%20novel%20potential%20of%20these%20natural%20resources%20for%20green%20chemistry.%20Taking%20advantage%20of%20the%20remarkable%20ability%20of%20the%20selected%20plants%20to%20accumulate%20Cu%28ii%29%20species%20into%20their%20roots%20or%20leaves%2C%20the%20latter%20can%20be%20directly%20used%20for%20the%20preparation%20of%20ecocatalysts%2C%20called%20Eco-Cu%5Cu00ae.%20The%20formed%20Eco-Cu%5Cu00ae%20catalysts%20are%20thoroughly%20characterized%20via%20ICP-MS%2C%20IR%20studies%20of%20pyridine%20sorption%5C%2Fdesorption%2C%20TEM%2C%20XRD%2C%20SM%20and%20model%20reactions%2C%20in%20order%20to%20elucidate%20the%20chemical%20composition%20and%20catalytic%20activity%20of%20these%20new%20materials.%20Significant%20differences%20of%20properties%20and%20activities%20were%20observed%20between%20Eco-Cu%5Cu00ae%20and%20conventional%20Cu%20catalysts.%20Eco-Cu%5Cu00ae%20are%20highly%20active%20catalysts%20in%20Ullmann%20coupling%20reactions%20with%20lower%20Cu%20quantities%20compared%20to%20known%20copper%20catalysts.%20%5Cu00a9%202016%20The%20Royal%20Society%20of%20Chemistry.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fc6ra08664k%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22PMI6NGAF%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Grison%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BC.%20Grison%2C%20V.%20Escande%20and%20T.%20K.%20Olszewski%2C%20in%20%26lt%3Bi%26gt%3BBioremediation%20and%20Bioeconomy%26lt%3B%5C%2Fi%26gt%3B%2C%202016%2C%20pp.%20629%26%23x2013%3B663.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DPMI6NGAF%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22bookSection%22%2C%22title%22%3A%22Ecocatalysis%3A%20A%20new%20approach%20toward%20bioeconomy%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Escande%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22Reconquest%20of%20biodiversity%2C%20remediation%20of%20anthropic%20and%20degraded%20sites%2C%20prevention%20of%20environmental%20health%20hazards%2C%20eco-innovation%2C%20green%20industry...%20Current%20ambitions%20are%20closely%20related%20to%20an%20interdisciplinary%20approach%20to%20scientific%20ecology%20able%20to%20participate%20in%20expected%20industrial%20renewal.%20In%20this%20chapter%20we%20will%20show%20how%20the%20unusual%20combination%20of%20phytotechnologies%20adapted%20to%20pollution%20and%20ecological%20rehabilitation%20of%20polluted%20sites%2C%20and%20enhancement%20of%20these%20processes%20through%20innovative%20green%20chemistry%2C%20can%20contribute%20to%20the%20current%20development%20of%20scientific%2C%20economic%2C%20and%20environmental%20priorities%20of%20eco-innovation%2C%20biomass%20conversion%2C%20and%20the%20transition%20from%20fossil%20resources%20to%20renewables.%20%5Cu00a9%202016%20Elsevier%20Inc.%20All%20rights%20reserved.%22%2C%22bookTitle%22%3A%22Bioremediation%20and%20Bioeconomy%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22%22%2C%22ISBN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A24Z%22%7D%7D%2C%7B%22key%22%3A%22UGU92BVR%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pi%5Cu0119ta%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A4%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Pi%26%23x119%3Bta%2C%20E.%20Proniewicz%2C%20A.%20Kudelski%2C%20T.%20K.%20Olszewski%20and%20B.%20Boduszek%2C%20Vibrational%20characterization%20of%20%26%23x3B1%3B-aminophosphinic%20acid%20derivatives%20of%20pyridine%3A%20DFT%2C%20Raman%20and%20SERS%20spectroscopy%20studies%2C%20%26lt%3Bi%26gt%3BVibrational%20Spectroscopy%26lt%3B%5C%2Fi%26gt%3B%2C%202016%2C%20%26lt%3Bb%26gt%3B83%26lt%3B%5C%2Fb%26gt%3B%2C%20115%26%23x2013%3B125.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DUGU92BVR%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Vibrational%20characterization%20of%20%5Cu03b1-aminophosphinic%20acid%20derivatives%20of%20pyridine%3A%20DFT%2C%20Raman%20and%20SERS%20spectroscopy%20studies%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Pi%5Cu0119ta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Kudelski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%5D%2C%22abstractNote%22%3A%22This%20paper%20shows%20Fourier-transform%20Raman%20%28FT-RS%29%20and%20surface-enhanced%20Raman%20spectroscopy%20%28SERS%29%20studies%20of%20three%20%5Cu03b1-aminophosphinic%20acid%20derivatives%20of%20pyridine%3A%20%5B%28butylamino%29%28pyridin-2-yl%29methyl%5Dphenylphosphinic%20acid%20%28%5Cu03b1-PyNH%29%2C%20%5B%28butylamino%29%28pyridin-3-yl%29methyl%5Dphenylphosphinic%20acid%20%28%5Cu03b2-PyNH%29%2C%20and%20%5B%28benzylamino%29%28pyridin-4-yl%29methyl%5Dphenylphosphinic%20acid%20%28%5Cu03b3-PyNH%29%20immobilized%20onto%20colloidal%20sol%20nanoparticles%20and%20electrochemically%20roughened%20surface%20of%20silver.%20The%20molecular%20geometries%20and%20vibrational%20wavenumbers%20were%20calculated%20based%20on%20density%20functional%20theory%20%28DFT%29%20at%20the%20B3LYP%206-311G%28df%2Cp%29%20level%20of%20theory.%20Based%20on%20the%20comparison%20of%20the%20FT-RS%20experimental%20and%20theoretical%20vibrational%20bands%20with%20the%20SERS%20results%20the%20orientation%20of%20the%20%5Cu03b1-aminophosphinic%20acid%20derivatives%20of%20pyridine%20onto%20two%20silver%20substrates%20was%20proposed.%20The%20changes%20in%20the%20adsorption%20process%20under%20the%20influence%20of%20the%20position%20of%20substituent%20in%20regard%20to%20the%20ring%20N%20atom%20%28in%20%5Cu03b1-%2C%20%5Cu03b2-%2C%20and%20%5Cu03b3-positions%2C%20respectively%29%20and%20modification%20of%20the%20substituent%20%28replacement%20of%20the%20butyl%20chain%20by%20the%20phenyl%20ring%20of%20high%20affinity%20to%20silver%20%28%5Cu03b3-PyNH%29%29%20were%20also%20discussed.%20%5Cu00a9%202016%20Elsevier%20B.V.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.vibspec.2016.02.001%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A36Z%22%7D%7D%2C%7B%22key%22%3A%22ZNQE9MR5%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Boduszek%20and%20Olszewski%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A5%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BB.%20Boduszek%20and%20T.%20K.%20Olszewski%2C%20Application%20of%20tris%28trimethylsilyl%29%20phosphite%20as%20a%20convenient%20phosphorus%20nucleophile%20in%20the%20direct%20synthesis%20of%20tetrasubstituted%20%26%23x3B1%3B-aminophosphonic%20acids%20from%20ketimines%2C%20%26lt%3Bi%26gt%3BArkivoc%26lt%3B%5C%2Fi%26gt%3B%2C%202016%2C%20%26lt%3Bb%26gt%3B2017%26lt%3B%5C%2Fb%26gt%3B%2C%20173%26%23x2013%3B179.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DZNQE9MR5%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Application%20of%20tris%28trimethylsilyl%29%20phosphite%20as%20a%20convenient%20phosphorus%20nucleophile%20in%20the%20direct%20synthesis%20of%20tetrasubstituted%20%5Cu03b1-aminophosphonic%20acids%20from%20ketimines%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22The%20condensation%20of%20tris%28trimethylsilyl%29%20phosphite%20with%20various%20ketimines%20leads%20directly%20to%20tetrasubstituted%20a-aminophosphonic%20acids.%20The%20presented%20reaction%20proceeds%20readily%20at%20room%20temperature%20and%20provides%20labile%20silylated%20esters%20of%20tetrasubstituted%20a-aminophosphonic%20acids%2C%20as%20non-isolable%20reaction%20intermediates.%20Subsequent%20methanolysis%20of%20the%20latter%20provides%20the%20desired%20%5Cu00e1-aminophosphonic%20acids%20bearing%20an%20fully%20substituted%20%5Cu00e1-carbon%20in%20good%20overall%20yields%20as%20crystalline%20non-hygroscopic%20solids%20after%20simple%20recrystallization%20from%20a%20methanol-acetone%20mixture.nordstom.%20%5Cu00a9%20ARKAT%20USA%2C%20Inc.%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.3998%5C%2Fark.5550190.p009.773%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22FJWULGZX%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Klem-Marciniak%20et%20al.%22%2C%22parsedDate%22%3A%222016%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Klem-Marciniak%2C%20T.%20K.%20Olszewski%2C%20K.%20Hoffmann%2C%20M.%20Huculak-M%26%23x105%3Bczka%20and%20D.%20M.%20Pop%26%23x142%3Bawski%2C%20Zastosowanie%20reakcji%20Mannicha%20do%20otrzymania%20chelat%26%23xF3%3Bw%20nawozowych%20%5C%2F%2C%20%26lt%3Bi%26gt%3BProceedings%20of%20ECOpole.%26lt%3B%5C%2Fi%26gt%3B%2C%20%2C%20DOI%3A10.2429%5C%2Fproc.2016.10%281%29019.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DFJWULGZX%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Zastosowanie%20reakcji%20Mannicha%20do%20otrzymania%20chelat%5Cu00f3w%20nawozowych%20%5C%2F%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ewelina%22%2C%22lastName%22%3A%22Klem-Marciniak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krystyna%22%2C%22lastName%22%3A%22Hoffmann%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marta%22%2C%22lastName%22%3A%22Huculak-M%5Cu0105czka%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dariusz%20M.%22%2C%22lastName%22%3A%22Pop%5Cu0142awski%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222016%22%2C%22language%22%3A%22pol%22%2C%22DOI%22%3A%2210.2429%5C%2Fproc.2016.10%281%29019%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-02T13%3A29%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22TMR3PR97%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20E.%20Wojaczy%26%23x144%3Bska%2C%20R.%20Wieczorek%20and%20J.%20B%26%23x105%3Bkowicz%2C%20%26%23x3B1%3B-Hydroxyphosphonic%20acid%20derivatives%20of%202-azanorbornane%3A%20Synthesis%2C%20DFT%20calculations%2C%20and%20crystal%20structure%20analysis%2C%20%26lt%3Bi%26gt%3BTetrahedron%20Asymmetry%26lt%3B%5C%2Fi%26gt%3B%2C%202015%2C%20%26lt%3Bb%26gt%3B26%26lt%3B%5C%2Fb%26gt%3B%2C%20601%26%23x2013%3B607.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DTMR3PR97%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22%5Cu03b1-Hydroxyphosphonic%20acid%20derivatives%20of%202-azanorbornane%3A%20Synthesis%2C%20DFT%20calculations%2C%20and%20crystal%20structure%20analysis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22R.%22%2C%22lastName%22%3A%22Wieczorek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22B%5Cu0105kowicz%22%7D%5D%2C%22abstractNote%22%3A%22Highly%20diastereoselective%20hydrophosphonylation%20of%202-azanorbornane%20aldehyde%20exo-1%20with%20silylated%20phosphorus%20esters%20yielded%20the%20%28S%29-%5Cu03b1-hydroxyphosphonic%20acid%20exo-3a.%20The%20use%20of%20endo-2%20gives%20the%20isomer%20with%20the%20opposite%20configuration%20at%20the%20new%20stereogenic%20center%20%28R%29-endo-4a.%20X-ray%20analysis%20revealed%20that%20exo-3a%20crystallizes%20in%20the%20orthorhombic%20space%20group%20P212121%20with%20two%20crystallographically%20independent%20molecules%2C%20one%20zwitterionic%20and%20the%20other%20forming%20a%20salt%20with%20HBr.%20%5Cu00a9%202015%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tetasy.2015.04.012%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%22UL3NK4XX%22%5D%2C%22dateModified%22%3A%222020-06-07T11%3A22%3A39Z%22%7D%7D%2C%7B%22key%22%3A%22XCWH74PB%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20Asymmetric%20synthesis%20of%20%26%23x3B1%3B-hydroxymethylphosphonates%20and%20phosphonic%20acids%20via%20hydrophosphonylation%20of%20aldehydes%20with%20chiral%20H-phosphonate%2C%20%26lt%3Bi%26gt%3BTetrahedron%20Asymmetry%26lt%3B%5C%2Fi%26gt%3B%2C%202015%2C%20%26lt%3Bb%26gt%3B26%26lt%3B%5C%2Fb%26gt%3B%2C%20393%26%23x2013%3B399.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DXCWH74PB%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Asymmetric%20synthesis%20of%20%5Cu03b1-hydroxymethylphosphonates%20and%20phosphonic%20acids%20via%20hydrophosphonylation%20of%20aldehydes%20with%20chiral%20H-phosphonate%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22Diastereoselective%20hydrophosphonylation%20of%20aldehydes%20with%20a%20chiral%20H-phosphonate%20is%20described.%20High%20asymmetric%20inductions%20were%20obtained%20using%20a%20readily%20available%20TADDOL%20auxiliary.%20Subsequent%2C%20racemization-free%20removal%20of%20the%20chiral%20auxiliary%20led%20to%20the%20desired%20%5Cu03b1-hydroxyphosphonic%20acids%20in%20very%20good%20yields%20and%20high%20enantiomeric%20purity%20as%20the%20%28R%29-enantiomers.%20%5Cu00a9%202015%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tetasy.2015.03.002%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A08Z%22%7D%7D%2C%7B%22key%22%3A%22NQFRT5IG%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pi%5Cu0119ta%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Pi%26%23x119%3Bta%2C%20E.%20Proniewicz%2C%20B.%20Boduszek%2C%20T.%20K.%20Olszewski%2C%20M.%20Nattich-Rak%20and%20Y.%20Kim%2C%20Probing%20the%20Ag%2C%20Au%2C%20and%20Cu%20electrode%5C%2Fpyridine-%26%23x3B1%3B-hydroxymethyl%20biphenyl%20phosphine%20oxide%20isomer%20interface%20with%20SERS%2C%20%26lt%3Bi%26gt%3BApplied%20Surface%20Science%26lt%3B%5C%2Fi%26gt%3B%2C%202015%2C%20%26lt%3Bb%26gt%3B335%26lt%3B%5C%2Fb%26gt%3B%2C%20167%26%23x2013%3B183.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DNQFRT5IG%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Probing%20the%20Ag%2C%20Au%2C%20and%20Cu%20electrode%5C%2Fpyridine-%5Cu03b1-hydroxymethyl%20biphenyl%20phosphine%20oxide%20isomer%20interface%20with%20SERS%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Pi%5Cu0119ta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Nattich-Rak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Kim%22%7D%5D%2C%22abstractNote%22%3A%22The%20potential-dependent%20surface%20enhanced%20Raman%20scattering%20%28SERS%29%20and%20generalized%20two-dimensional%20correlation%20analysis%20%28G2DCA%29%20methods%20were%20used%20to%20characterize%20three%20pyridine-%5Cu03b1-hydroxymethyl%20biphenyl%20phosphine%20oxide%20isomers%3A%20%28diphenylphosphoryl%29%28pyridine-2-yl%29methanol%20%28%5Cu03b1-Py%29%2C%20%28diphenylphosphoryl%29%28pyridine-3-yl%29methanol%20%28%5Cu03b2-Py%29%2C%20and%20%28diphenylphosphoryl%29%28pyridine-4-yl%29methanol%20%28%5Cu03b3-Py%29.%20The%20aforementioned%20compounds%20were%20deposited%20onto%20Ag%2C%20Au%2C%20and%20Cu%20electrode%20surfaces%20under%20different%20applied%20electrode%20potentials%20in%20an%20aqueous%20solution%20at%20physiological%20pH.%20On%20the%20basis%20of%20the%20enhancement%2C%20broadening%2C%20and%20shift%20in%20wavenumbers%20of%20individual%20bands%2C%20the%20geometry%20of%20the%20investigated%20molecules%20and%20influence%20of%20substituent%20position%20on%20the%20adsorption%20mode%20%28in%20the%20%5Cu03b1-%282-%29%2C%20%5Cu03b2-%283-%29%2C%20and%20%5Cu03b3-%284-%29%20positions%29%2C%20electrode%20type%2C%20and%20applied%20electrode%20potential%20were%20examined.%20It%20was%20found%20that%20the%20SERS%20spectra%20are%20dominated%20by%20bands%20assigned%20to%20phenyl%20%28Ph%29%20and%20pyridine%20%28Py%29%20ring%20vibrations.%20However%2C%20some%20differences%20in%20the%20arrangement%20of%20the%20aforementioned%20fragments%20were%20observed%20with%20changes%20to%20the%20type%20of%20the%20metal%20surface%20and%20the%20applied%20electrode%20potential.%20%5Cu00a9%202015%20Elsevier%20B.V.%20All%20rights%20reserved.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.apsusc.2015.02.048%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A24%3A56Z%22%7D%7D%2C%7B%22key%22%3A%223ZC4UE6G%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Escande%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BV.%20Escande%2C%20T.%20K.%20Olszewski%20and%20C.%20Grison%2C%20From%20biodiversity%20to%20catalytic%20diversity%3A%20how%20to%20control%20the%20reaction%20mechanism%20by%20the%20nature%20of%20metallophytes%2C%20%26lt%3Bi%26gt%3BEnvironmental%20Science%20and%20Pollution%20Research%26lt%3B%5C%2Fi%26gt%3B%2C%202015%2C%20%26lt%3Bb%26gt%3B22%26lt%3B%5C%2Fb%26gt%3B%2C%205653%26%23x2013%3B5666.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D3ZC4UE6G%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22From%20biodiversity%20to%20catalytic%20diversity%3A%20how%20to%20control%20the%20reaction%20mechanism%20by%20the%20nature%20of%20metallophytes%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Escande%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22Phytoextraction%20is%20widely%20used%20for%20the%20reclamation%20of%20degraded%20sites%2C%20particularly%20to%20remove%20trace%20metals%20from%20contaminated%20soils.%20Whereas%20this%20technique%20demonstrates%20several%20advantages%2C%20the%20biomass%20resulting%20from%20phytoextraction%20processes%20is%20highly%20enriched%20in%20metallic%20elements%20and%20constitutes%20therefore%20a%20problematic%20waste.%20We%20show%20here%20that%20this%20biomass%20can%20be%20used%20for%20the%20preparation%20of%20novel%20polymetallic%20extracts%2C%20with%20high%20potential%20as%20catalysts%5Cu00a0or%20reagents%20in%20organic%20synthesis.%20This%20new%20concept%20of%20ecocatalysis%20constitutes%20an%20innovative%20recycling%20of%20metallic%20elements%20whose%20current%20known%20reserves%20could%20be%20exhausted%20in%20the%20coming%20decades.%20The%20ecocatalysts%20Eco-Zn%20and%20Eco-Ni%20prepared%20respectively%20from%20Zn%20and%20Ni%20hyperaccumulating%20plants%20display%20two%20distinct%20chemical%20reactivities%2C%20starting%20from%20the%20same%20substrates.%20Eco-Zn%20led%20to%20the%20formation%20of%20esters%20of%20commercial%20interest%20for%20the%20fragrance%20industry%2C%20following%20a%20hydro-acyloxy-addition%20reaction%20pathway.%20In%20contrast%2C%20Eco-Ni%20afforded%20chlorinated%20products%20thank%20to%20the%20hydrochlorination%20of%20alkenes.%20Both%20ecocatalysts%20allowed%20the%20synthesis%20of%20valuable%20products%20in%20high%20yields%20through%20methodologies%20in%20line%20with%20the%20spirit%20of%20sustainable%20chemistry.%20%5Cu00a9%202014%2C%20Springer-Verlag%20Berlin%20Heidelberg.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1007%5C%2Fs11356-014-3483-6%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A13Z%22%7D%7D%2C%7B%22key%22%3A%22AZIDJUIF%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Wojaczy%5Cu0144ska%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Wojaczy%26%23x144%3Bska%2C%20J.%20Wojaczy%26%23x144%3Bski%2C%20K.%20Kleniewska%2C%20M.%20Dorsz%20and%20T.%20K.%20Olszewski%2C%202-Azanorbornane-a%20versatile%20chiral%20aza-Diels-Alder%20cycloadduct%3A%20Preparation%2C%20applications%20in%20stereoselective%20synthesis%20and%20biological%20activity%2C%20%26lt%3Bi%26gt%3BOrganic%20and%20Biomolecular%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202015%2C%20%26lt%3Bb%26gt%3B13%26lt%3B%5C%2Fb%26gt%3B%2C%206116%26%23x2013%3B6148.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DAZIDJUIF%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%222-Azanorbornane-a%20versatile%20chiral%20aza-Diels-Alder%20cycloadduct%3A%20Preparation%2C%20applications%20in%20stereoselective%20synthesis%20and%20biological%20activity%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Wojaczy%5Cu0144ski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Kleniewska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Dorsz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22The%20review%20presents%20the%20achievements%20in%20the%20field%20of%20preparation%20of%20chiral%202-azanorbornyl%20derivatives%20and%20their%20application%20in%20various%20stereoselective%20reactions%20as%20well%20as%20in%20biomimetic%20studies.%20This%20journal%20is%20%5Cu00a9%20The%20Royal%20Society%20of%20Chemistry%202015.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fc5ob00173k%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%22UL3NK4XX%22%5D%2C%22dateModified%22%3A%222020-06-07T11%3A22%3A34Z%22%7D%7D%2C%7B%22key%22%3A%22JKHDQCXN%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20and%20Majewski%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%20and%20M.%20Majewski%2C%20Highly%20diastereoselective%20addition%20of%20chiral%20H-phosphonate%20to%20tert-butylsulfinyl%20aldimines%3A%20a%20convenient%20approach%20to%20%28R%29-%26%23x3B1%3B-aminophosphonic%20acids%2C%20%26lt%3Bi%26gt%3BTetrahedron%20Asymmetry%26lt%3B%5C%2Fi%26gt%3B%2C%202015%2C%20%26lt%3Bb%26gt%3B26%26lt%3B%5C%2Fb%26gt%3B%2C%20846%26%23x2013%3B852.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DJKHDQCXN%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Highly%20diastereoselective%20addition%20of%20chiral%20H-phosphonate%20to%20tert-butylsulfinyl%20aldimines%3A%20a%20convenient%20approach%20to%20%28R%29-%5Cu03b1-aminophosphonic%20acids%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Majewski%22%7D%5D%2C%22abstractNote%22%3A%22Abstract%20A%20highly%20diastereoselective%20nucleophilic%20addition%20of%20chiral%20H-phosphonate%2C%20derived%20from%20a%20readily%20available%20TADDOL%20auxiliary%2C%20to%20%28S%29-N-tert-butylsulfinyl%20aldimines%20is%20reported.%20The%20reaction%20proceeds%20at%20room%20temperature%20in%20the%20presence%20of%20potassium%20carbonate%20and%20yields%20the%20corresponding%20aliphatic%2C%20aromatic%20and%20heteroaromatic%20%5Cu03b1-aminophosphonates%20with%20dr%20%26gt%3B95%3A5.%20Subsequent%20simultaneous%20removal%20of%20both%20chiral%20auxiliaries%20leads%20to%20the%20desired%20%5Cu03b1-aminophosphonic%20acids%20in%20very%20good%20yields%20with%20an%20%28R%29-configuration%20at%20the%20stereogenic%20%5Cu03b1%20carbon.%20%5Cu00a9%202015%20Elsevier%20Ltd.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tetasy.2015.06.008%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A05Z%22%7D%7D%2C%7B%22key%22%3A%22DJTI6TXL%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Klem-Marciniak%20et%20al.%22%2C%22parsedDate%22%3A%222015%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Klem-Marciniak%2C%20T.%20K.%20Olszewski%20and%20M.%20Huculak-M%26%23x105%3Bczka%2C%20in%20%26lt%3Bi%26gt%3BNauka%20i%20przemys%26%23x142%3B%20-%20metody%20spektroskopowe%20w%20praktyce%2C%20nowe%20wyzwania%20i%20mo%26%23x17C%3Bliwo%26%23x15B%3Bci%26%23x202F%3B%3A%20praca%20zbiorowa.%20T.%201%20%5C%2F%20pod%20red.%20Zbigniewa%20Hubickiego.%3A%20Lublin%26%23x202F%3B%3A%20Uniwersytet%20Marii%20Curie-Sk%26%23x142%3Bodowskiej%2C%202015.%26lt%3B%5C%2Fi%26gt%3B%2C%202015.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DDJTI6TXL%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22bookSection%22%2C%22title%22%3A%22Metody%20syntezy%20nawozowych%20substancji%20chelatuj%5Cu0105cych%20-%20EDDHA%2C%20EDDHSA%20%5C%2F%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Ewelina%22%2C%22lastName%22%3A%22Klem-Marciniak%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Marta%22%2C%22lastName%22%3A%22Huculak-M%5Cu0105czka%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22bookTitle%22%3A%22Nauka%20i%20przemys%5Cu0142%20-%20metody%20spektroskopowe%20w%20praktyce%2C%20nowe%20wyzwania%20i%20mo%5Cu017cliwo%5Cu015bci%20%3A%20praca%20zbiorowa.%20T.%201%20%5C%2F%20pod%20red.%20Zbigniewa%20Hubickiego.%3A%20Lublin%20%3A%20Uniwersytet%20Marii%20Curie-Sk%5Cu0142odowskiej%2C%202015.%22%2C%22date%22%3A%222015%22%2C%22language%22%3A%22pol%22%2C%22ISBN%22%3A%229788393946%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%2C%22FCESI3IL%22%5D%2C%22dateModified%22%3A%222020-06-02T13%3A27%3A37Z%22%7D%7D%2C%7B%22key%22%3A%22RGEVGE4C%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Pi%5Cu0229ta%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A3%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Pi%26%23x229%3Bta%2C%20E.%20Proniewicz%2C%20B.%20Boduszek%2C%20T.%20K.%20Olszewski%2C%20Y.%20Kim%20and%20L.%20M.%20Proniewicz%2C%20Exploring%20the%20isomer%20dependent%20SERS%20spectra%20of%20%28diphenylphosphoryl%29%20%28pyridin-2%2C%20-3%2C%20and%20-4-yl%29methanol%20adsorbed%20on%20gold%20nanocolloids%2C%20%26lt%3Bi%26gt%3BJournal%20of%20Spectroscopy%26lt%3B%5C%2Fi%26gt%3B%2C%20%2C%20DOI%3A10.1155%5C%2F2014%5C%2F894749.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DRGEVGE4C%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Exploring%20the%20isomer%20dependent%20SERS%20spectra%20of%20%28diphenylphosphoryl%29%20%28pyridin-2%2C%20-3%2C%20and%20-4-yl%29methanol%20adsorbed%20on%20gold%20nanocolloids%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Pi%5Cu0229ta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.M.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%5D%2C%22abstractNote%22%3A%22The%20surface-enhanced%20Raman%20scattering%20%28SERS%29%20spectra%20of%20three%20aminophosphonate%20derivatives%20of%20pyridine%3A%20%28diphenylphosphoryl%29%28pyridin-2-yl%29%20methanol%20%28%5Cu03b1%20-Pyr%29%2C%20%28diphenylphosphoryl%29%28pyridin-3-yl%29methanol%20%28%5Cu03b2%20-Pyr%29%2C%20and%20%28diphenylphosphoryl%29%28pyridin-4-yl%29methanol%20%28%5Cu03b3%20-Pyr%29%20were%20measured%20after%20immobilization%20onto%20colloidal%20gold%20surface.%20Changes%20in%20the%20wavenumber%2C%20broadness%2C%20and%20enhancement%20between%20the%20corresponding%20Raman%20and%20SERS%20bands%20allowed%20to%20deduce%20orientation%20of%20the%20%5Cu03b1%20-%2C%20%5Cu03b2%20-%2C%20and%20%5Cu03b3%20-isomers%20%28%5Cu03b1%20-%2C%20%5Cu03b2%20-%2C%20and%20%5Cu03b3%20-refer%20to%20the%20position%20of%20the%20substituent%20relative%20to%20the%20ring%20nitrogen%20atom%29%20of%20aminophosphonate%20derivatives%20of%20pyridine%20on%20the%20gold%20surface.%20Briefly%2C%20it%20was%20demonstrated%20that%20the%20%5Cu03b1%20-Pyr%20and%20%5Cu03b2%20-Pyr%20show%20the%20same%20mode%20of%20adsorption%2C%20whereas%20the%20adsorption%20process%20of%20the%20%5Cu03b3%20-Pyr%20isomer%20differs%20in%20this%20regard%20that%20pyridine%20assists%20in%20the%20interaction%20with%20the%20gold%20surface.%20%5Cu00a9%202014%20Ewa%20Pi%5Cu0229ta%20et%20al.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1155%5C%2F2014%5C%2F894749%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22XCP5IBEV%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Skowerski%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BK.%20Skowerski%2C%20J.%20Bia%26%23x142%3Becki%2C%20A.%20Tracz%20and%20T.%20K.%20Olszewski%2C%20An%20attempt%20to%20provide%20an%20environmentally%20friendly%20solvent%20selection%20guide%20for%20olefin%20metathesis%2C%20%26lt%3Bi%26gt%3BGreen%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202014%2C%20%26lt%3Bb%26gt%3B16%26lt%3B%5C%2Fb%26gt%3B%2C%201125%26%23x2013%3B1130.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DXCP5IBEV%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22An%20attempt%20to%20provide%20an%20environmentally%20friendly%20solvent%20selection%20guide%20for%20olefin%20metathesis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Skowerski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Bia%5Cu0142ecki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Tracz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22A%20range%20of%20environmentally%20conservative%20solvents%20was%20evaluated%20for%20application%20in%20olefin%20metathesis.%20Different%20commercially%20available%20and%20most%20frequently%20applied%20ruthenium%20catalysts%20were%20employed.%20The%20data%20obtained%20can%20be%20used%20as%20a%20guide%20to%20facilitate%20replacement%20of%20environmentally%20detrimental%20chlorinated%20or%20aromatic%20solvents%20with%20greener%20reaction%20media%20in%20order%20to%20make%20applications%20of%20olefin%20metathesis%20in%20both%20industry%20and%20academia%20more%20environmentally%20benign%20and%20sustainable%20processes.%20%5Cu00a9%202014%20The%20Royal%20Society%20of%20Chemistry.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1039%5C%2Fc3gc41943f%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A18Z%22%7D%7D%2C%7B%22key%22%3A%22L9EDUG9E%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Proniewicz%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BE.%20Proniewicz%2C%20E.%20Pieta%2C%20K.%20Zborowski%2C%20A.%20Kudelski%2C%20B.%20Boduszek%2C%20T.%20K.%20Olszewski%2C%20Y.%20Kim%20and%20L.%20M.%20Proniewicz%2C%20Raman%2C%20surface-enhanced%20raman%2C%20and%20density%20functional%20theory%20characterization%20of%20%28diphenylphosphoryl%29%28pyridin-2-%2C%20-3-%2C%20and%20-4-yl%29methanol%2C%20%26lt%3Bi%26gt%3BJournal%20of%20Physical%20Chemistry%20A%26lt%3B%5C%2Fi%26gt%3B%2C%202014%2C%20%26lt%3Bb%26gt%3B118%26lt%3B%5C%2Fb%26gt%3B%2C%205614%26%23x2013%3B5625.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DL9EDUG9E%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Raman%2C%20surface-enhanced%20raman%2C%20and%20density%20functional%20theory%20characterization%20of%20%28diphenylphosphoryl%29%28pyridin-2-%2C%20-3-%2C%20and%20-4-yl%29methanol%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Pieta%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Zborowski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22A.%22%2C%22lastName%22%3A%22Kudelski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Y.%22%2C%22lastName%22%3A%22Kim%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22L.M.%22%2C%22lastName%22%3A%22Proniewicz%22%7D%5D%2C%22abstractNote%22%3A%22This%20work%20presents%20near-infrared%20Raman%20spectroscopy%20%28FT-RS%29%20and%20surface-enhanced%20Raman%20scattering%20%28SERS%29%20studies%20of%20three%20pyridine-%5Cu03b1-%20hydroxymethyl%20biphenyl%20phosphine%20oxide%20isomers%3A%20%28diphenylphosphoryl%29%28pyridin-2-%20yl%29methanol%20%28%5Cu03b1-Py%29%2C%20%28diphenylphosphoryl%29%28pyridin-3-yl%29methanol%20%28%5Cu03b2-Py%29%2C%20and%20%28diphenylphosphoryl%29%28pyridin-4-yl%29methanol%20%28%5Cu03b3-Py%29%20adsorbed%20onto%20colloidal%20and%20roughened%20in%20oxidation-reduction%20cycles%20silver%20surfaces.%20The%20molecular%20geometries%20in%20the%20equilibrium%20state%20and%20vibrational%20frequencies%20were%20calculated%20by%20density%20functional%20theory%20%28DFT%29%20at%20the%20B3LYP%206-311G%28df%2Cp%29%20level%20of%20theory.%20The%20results%20imply%20that%20the%20most%20stable%20structure%20of%20the%20investigated%20molecules%20is%20a%20dimer%20created%20by%20two%20intermolecular%20hydrogen%20bonds%20between%20the%20H%20atom%20of%20the%20%5Cu03b1-hydroxyl%20group%20%28in%20up%20%28HOU%29%20or%20down%20%28HOD%29%20stereo%20bonds%20position%29%20and%20the%20O%20atom%20of%20tertiary%20phosphine%20oxide%20%28%3DO%29%20of%20the%20two%20monomers.%20Comparison%20the%20FT-RS%20spectra%20with%20the%20respective%20SERS%20spectra%20allowed%20us%20to%20predict%20the%20orientation%20of%20the%20hydroxyphosphonate%20derivatives%20of%20pyridine%20that%20depends%20upon%20both%20the%20position%20of%20the%20substituent%20relative%20to%20the%20ring%20N%20atom%20%28in%20%5Cu03b1-%2C%20%5Cu03b2-%2C%20and%20%5Cu03b3-position%2C%20respectively%29%20and%20the%20type%20of%20silver%20substrate.%20%5Cu00a9%202014%20American%20Chemical%20Society.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fjp503392e%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A22Z%22%7D%7D%2C%7B%22key%22%3A%227AUZ2FXG%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Escande%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BV.%20Escande%2C%20T.%20K.%20Olszewski%2C%20E.%20Petit%20and%20C.%20Grison%2C%20Biosourced%20polymetallic%20catalysts%3A%20An%20efficient%20means%20to%20synthesize%20underexploited%20platform%20molecules%20from%20carbohydrates%2C%20%26lt%3Bi%26gt%3BChemSusChem%26lt%3B%5C%2Fi%26gt%3B%2C%202014%2C%20%26lt%3Bb%26gt%3B7%26lt%3B%5C%2Fb%26gt%3B%2C%201915%26%23x2013%3B1923.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D7AUZ2FXG%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Biosourced%20polymetallic%20catalysts%3A%20An%20efficient%20means%20to%20synthesize%20underexploited%20platform%20molecules%20from%20carbohydrates%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Escande%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22E.%22%2C%22lastName%22%3A%22Petit%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22Polymetallic%20hyperaccumulating%20plants%20growing%20on%20wastes%20from%20former%20mining%20activity%20were%20used%20as%20the%20starting%20material%20in%20the%20preparation%20of%20novel%20plant-based%20Lewis%20acid%20catalysts.%20The%20preparation%20of%20biosourced%20Lewis%20acid%20catalysts%20is%20a%20new%20way%20to%20make%20use%20of%20mining%20wastes.%20These%20catalysts%20were%20characterized%20by%20X-ray%20fluorescence%2C%20X-ray%20diffraction%2C%20inductively%20coupled%20plasma%20mass%20spectrometry%2C%20and%20direct%20infusion%20electrospray%20ionization%20mass%20spectrometry.%20These%20analyses%20revealed%20a%20complex%20composition%20of%20metal%20species%2C%20present%20mainly%20as%20polymetallic%20chlorides.%20The%20catalysts%20proved%20to%20be%20efficient%20and%20recyclable%20in%20a%20solid-state%20version%20of%20the%20Garcia%20Gonzalez%20reaction%2C%20which%20has%20been%20underexploited%20until%20now%20in%20efforts%20to%20use%20carbohydrates%20from%20biomass.%20This%20methodology%20was%20extended%20to%20various%20carbohydrates%20to%20obtain%20the%20corresponding%20polyhydroxyalkyl%20furans%20in%2038-98%20%25%20yield.%20These%20plant-based%20catalysts%20may%20be%20a%20better%20alternative%20to%20classical%20Lewis%20acid%20catalysts%20that%20were%20previously%20used%20for%20the%20Garcia%20Gonzalez%20reaction%2C%20such%20as%20ZnCl2%2C%20FeCl3%2C%20and%20CeCl3%2C%20which%20are%20often%20unrecyclable%2C%20require%20aqueous%20treatments%2C%20or%20rely%20on%20metals%2C%20the%20current%20known%20reserves%20of%20which%20will%20be%20consumed%20in%20the%20coming%20decades.%20Moreover%2C%20the%20plant-based%20catalysts%20allowed%20novel%20control%20of%20the%20Garcia%20Gonzalez%20reaction%2C%20as%20two%20different%20products%20were%20obtained%20depending%20on%20the%20reaction%20conditions.%20Common-or-garden%20variety%20catalyst%3A%20Polymetallic%20hyperaccumulating%20plants%20are%20used%20in%20the%20preparation%20of%20Lewis%20acid%20plant-based%20catalysts.%20The%20catalysts%20efficiently%20mediate%20the%20Garcia%20Gonzalez%20reaction%20to%20furnish%20platform%20molecules%20from%20carbohydrates.%20Efficiency%2C%20generality%20of%20application%2C%20ease%20of%20control%20of%20the%20reaction%20selectivity%2C%20use%20of%20solid-state%20reactions%2C%20and%20the%20capacity%20to%20recover%20and%20reuse%20polymetallic%20catalysts%20are%20the%20key%20advantages%20of%20the%20presented%20approach.%20%5Cu00a9%202014%20WILEY-VCH%20Verlag%20GmbH%20%26amp%3B%20Co.%20KGaA%2C%20Weinheim.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fcssc.201400078%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A38Z%22%7D%7D%2C%7B%22key%22%3A%227NPYGZ2G%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Escande%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BV.%20Escande%2C%20T.%20K.%20Olszewski%20and%20C.%20Grison%2C%20Preparation%20of%20ecological%20catalysts%20derived%20from%20Zn%20hyperaccumulating%20plants%20and%20their%20catalytic%20activity%20in%20Diels-Alder%20reaction%2C%20%26lt%3Bi%26gt%3BComptes%20Rendus%20Chimie%26lt%3B%5C%2Fi%26gt%3B%2C%202014%2C%20%26lt%3Bb%26gt%3B17%26lt%3B%5C%2Fb%26gt%3B%2C%20731%26%23x2013%3B737.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D7NPYGZ2G%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Preparation%20of%20ecological%20catalysts%20derived%20from%20Zn%20hyperaccumulating%20plants%20and%20their%20catalytic%20activity%20in%20Diels-Alder%20reaction%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22V.%22%2C%22lastName%22%3A%22Escande%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22Zn%20hyperaccumulating%20plants%20Noccaea%20caerulescens%20and%20Anthyllis%20vulneraria%20were%20used%20as%20the%20starting%20material%20for%20preparation%20of%20novel%20Lewis%20ecological%20catalysts.%20Those%20catalysts%20efficiently%20mediate%20the%20Diels-Alder%20reaction.%20High%20yields%2C%20very%20good%20regio-%20and%20diastereoselectivity%2C%20low%20catalyst%20loading%20and%20the%20possibly%20of%20its%20recovery%20and%20reuse%2C%20along%20with%20mild%20reaction%20conditions%2C%20eco-friendly%20treatment%20and%20short%20reaction%20time%2C%20are%20the%20key%20advantages%20of%20the%20presented%20approach.%20%5Cu00a9%202013%20Acad%5Cu00e9mie%20des%20sciences.%20Published%20by%20Elsevier%20Masson%20SAS.%20All%20rights%20reserved.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.crci.2013.09.009%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A41Z%22%7D%7D%2C%7B%22key%22%3A%22TDAMNLMA%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20M.%20Figlus%20and%20M.%20Bieniek%2C%20Olefin%20metathesis%3A%20A%20versatile%20synthetic%20tool%20for%20use%20in%20preparation%20of%20active%20pharmaceutical%20ingredients%2C%20%26lt%3Bi%26gt%3BChimica%20Oggi%5C%2FChemistry%20Today%26lt%3B%5C%2Fi%26gt%3B%2C%202014%2C%20%26lt%3Bb%26gt%3B32%26lt%3B%5C%2Fb%26gt%3B%2C%2022%26%23x2013%3B29.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DTDAMNLMA%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Olefin%20metathesis%3A%20A%20versatile%20synthetic%20tool%20for%20use%20in%20preparation%20of%20active%20pharmaceutical%20ingredients%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Figlus%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Bieniek%22%7D%5D%2C%22abstractNote%22%3A%22Olefin%20metathesis%20is%20a%20powerful%20transformation%20based%20on%20catalytic%20reaction%20between%20alkenes.%20It%20allows%20a%20formation%20of%20a%20variety%20of%20structurally%20diverse%20molecules%20that%20cannot%20be%20easily%20prepared%20by%20alternative%20routes.%20Recently%20developed%20methods%20require%20relatively%20low%20catalyst%20loading%20and%20enable%20easy%20removal%20of%20residual%20ruthenium%20from%20the%20reaction%20product.%20These%20developments%20have%20attracted%20the%20attention%20of%20process%20chemists%20who%20add%20metathesis%20reaction%20to%20a%20toolbox%20of%20reliable%20methods%20for%20production%20of%20pharmaceuticals.%20This%20review%20presents%20selected%20examples%20of%20successful%20application%20of%20olefin%20metathesis%20in%20the%20synthesis%20of%20active%20pharmaceutical%20ingredients%20from%20laboratories%20within%20the%20pharmaceutical%20industry.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A30Z%22%7D%7D%2C%7B%22key%22%3A%222SRU7BWK%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%22%2C%22parsedDate%22%3A%222014%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20Environmentally%20benign%20syntheses%20of%20%26%23x3B1%3B-substituted%20phosphonates%3A%20Preparation%20of%20%26%23x3B1%3B-amino-%20and%20%26%23x3B1%3B-hydroxyphosphonates%20in%20water%2C%20in%20ionic%20liquids%2C%20and%20under%20solvent-free%20conditions%2C%20%26lt%3Bi%26gt%3BSynthesis%20%28Germany%29%26lt%3B%5C%2Fi%26gt%3B%2C%202014%2C%20%26lt%3Bb%26gt%3B46%26lt%3B%5C%2Fb%26gt%3B%2C%20403%26%23x2013%3B429.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D2SRU7BWK%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Environmentally%20benign%20syntheses%20of%20%5Cu03b1-substituted%20phosphonates%3A%20Preparation%20of%20%5Cu03b1-amino-%20and%20%5Cu03b1-hydroxyphosphonates%20in%20water%2C%20in%20ionic%20liquids%2C%20and%20under%20solvent-free%20conditions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22Due%20to%20the%20interest%20in%20%5Cu03b1-amino-%20and%20%5Cu03b1-hydroxyphosphonates%20and%20their%20derivatives%2C%20which%20arises%20from%20the%20important%20biological%20activity%20exhibited%20by%20those%20compounds%2C%20the%20development%20of%20efficient%20protocols%20for%20their%20preparation%20is%20of%20great%20importance.%20In%20the%20last%2010%20years%20however%2C%20the%20chemistry%20of%20%5Cu03b1-amino%20and%20%5Cu03b1-hydroxyphosphonates%20has%20been%20witness%20to%20an%20explosion%20of%20research%20activities%20in%20the%20field%20of%20application%20of%20environmentally%20benign%20media.%20This%20fact%20can%20be%20partially%20attributed%20to%20the%20development%20of%20the%20field%20of%20green%20and%20sustainable%20chemistry%20and%20especially%20the%20implementation%20of%20green%20solvents%20that%20has%20a%20large%20potential%20to%20contribute%20to%20more%20sustainable%20processes%20in%20chemical%2C%20pharmaceutical%20and%20processing%20industries.%20This%20review%20provides%20the%20reader%20with%20an%20in-depth%20overview%20of%20advances%20in%20the%20synthesis%20of%20%5Cu03b1-amino-%20and%20%5Cu03b1-hydroxyphosphonates%20under%20eco-friendy%20conditions%20compiled%20into%20sections%20with%20respect%20to%20product%20type%20and%20reaction%20medium.%201%20Introduction%202%20Syntheses%20of%20%5Cu03b1-Aminophosphonates%20in%20Environmentally%20Friendly%20Media%202.1%20Reactions%20in%20Water%202.2%20Reactions%20in%20Ionic%20Liquids%202.3%20Solvent-Free%20Protocols%202.3.1%20Reactions%20without%20Any%20Additives%202.3.2%20Reactions%20Promoted%20by%20Ultrasound%20or%20Microwave%20Irradiation%202.3.3%20Catalyzed%20Reactions%20under%20Solvent-Free%20Conditions%203%20Preparation%20of%20%5Cu03b1-Hydroxyphosphonates%20under%20Environmentally%20Friendly%20Conditions%203.1%20Reactions%20in%20Water%203.2%20Reactions%20under%20Solvent-Free%20Conditions%204%20Concluding%20Remarks.%20%5Cu00a9%202014%20Georg%20Thieme%20Verlag%20Stuttgart%20New%20York.%22%2C%22date%22%3A%222014%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1055%5C%2Fs-0033-1338588%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A33Z%22%7D%7D%2C%7B%22key%22%3A%22TA6DLHS9%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Skowerski%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BK.%20Skowerski%2C%20P.%20Kasprzycki%2C%20M.%20Bieniek%20and%20T.%20K.%20Olszewski%2C%20Efficient%2C%20durable%20and%20reusable%20olefin%20metathesis%20catalysts%20with%20high%20affinity%20to%20silica%20gel%2C%20%26lt%3Bi%26gt%3BTetrahedron%26lt%3B%5C%2Fi%26gt%3B%2C%202013%2C%20%26lt%3Bb%26gt%3B69%26lt%3B%5C%2Fb%26gt%3B%2C%207408%26%23x2013%3B7415.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DTA6DLHS9%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Efficient%2C%20durable%20and%20reusable%20olefin%20metathesis%20catalysts%20with%20high%20affinity%20to%20silica%20gel%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Skowerski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Kasprzycki%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Bieniek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22The%20new%20Scorpio%20type%20olefin%20metathesis%20catalysts%20with%20very%20high%20affinity%20to%20silica%20gel%20are%20reported.%20After%20completion%20of%20the%20reaction%2C%20those%20complexes%20can%20be%20efficiently%20separated%20from%20reaction%20product%20by%20direct%20filtration%20of%20reaction%20mixture%20through%20a%20short%20pad%20of%20silica%20gel.%20Products%20obtained%20by%20this%20methodology%20are%20contaminated%20with%20low%20amounts%20of%20residual%20ruthenium.%20Especially%2C%20catalyst%20%28H2IPr%29%28Cl%292Ru%3DC%28H%29%28C6H4OR%29%20%285b%2C%20R%3DCH%28Me%29%28C%28O%29N%28Me%29OMe%29%20exhibited%20very%20high%20activity%20and%20could%20be%20easily%20recovered%20and%20reused.%20Additionally%2C%20this%20catalyst%20was%20found%20to%20be%20effective%20already%20at%200.1-0.5%20mol%20%25%20and%20showed%20good%20compatibility%20with%20environmentally%20benign%20solvents.%20%5Cu00a9%202013%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tet.2013.06.056%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A47Z%22%7D%7D%2C%7B%22key%22%3A%22RLWLRVGZ%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222013%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20M.%20Bieniek%2C%20K.%20Skowerski%20and%20K.%20Grela%2C%20A%20new%20tool%20in%20the%20toolbox%3A%20Electron-withdrawing%20group%20activated%20-Ruthenium%20Catalysts%20for%20Olefin%20Metathesis%2C%20%26lt%3Bi%26gt%3BSynlett%26lt%3B%5C%2Fi%26gt%3B%2C%20%2C%20DOI%3A10.1055%5C%2Fs-0032-1318497.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DRLWLRVGZ%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20new%20tool%20in%20the%20toolbox%3A%20Electron-withdrawing%20group%20activated%20-Ruthenium%20Catalysts%20for%20Olefin%20Metathesis%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Bieniek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Skowerski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Grela%22%7D%5D%2C%22abstractNote%22%3A%22This%20account%20describes%20the%20discovery%20and%20development%20of%20efficient%20electron-withdrawing%20group%20activated%20Hoveyda-Grubbs%20catalysts%2C%20including%20a%20nitro-substituted%20catalyst%20and%20their%20applications%20in%20the%20syntheses%20of%20complex%20molecules.%201%20Introduction%202%20EWG-Activated%20Hoveyda-Grubbs%20Complexes%202.1%20The%20Discovery%20and%20the%20Story%20Behind%20It%202.2%20The%20Nitro-Substituted%20Hoveyda-Grubbs%20Catalyst%202.3%20pH-Responsive%20Catalysts%202.4%20Fine-Tuning%20of%20the%20EWG%20Fragment%203%20Applications%20of%20the%20Nitro-Substituted%20Hoveyda-Grubbs%20Catalyst%20in%20the%20Preparation%20of%20Compounds%20of%20Biological%20Relevance%203.1%20Synthesis%20of%20BILN%202061%204%20Concluding%20Remarks.%20%5Cu00a9%20Georg%20Thieme%20Verlag%20Stuttgart%20.%20New%20York.%22%2C%22date%22%3A%222013%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1055%5C%2Fs-0032-1318497%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A52Z%22%7D%7D%2C%7B%22key%22%3A%229FDCAMIS%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Boduszek%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BB.%20Boduszek%2C%20T.%20K.%20Olszewski%2C%20W.%20Goldeman%2C%20K.%20Grzegolec%20and%20P.%20Blazejewska%2C%20Preparation%20of%20new%20imidazol-2-yl-%28amino%29methylphosphonates%2C%20phosphinates%20and%20phosphine%20oxides%20and%20their%20unexpected%20cleavage%20under%20acidic%20conditions%2C%20%26lt%3Bi%26gt%3BTetrahedron%26lt%3B%5C%2Fi%26gt%3B%2C%202012%2C%20%26lt%3Bb%26gt%3B68%26lt%3B%5C%2Fb%26gt%3B%2C%201223%26%23x2013%3B1229.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D9FDCAMIS%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Preparation%20of%20new%20imidazol-2-yl-%28amino%29methylphosphonates%2C%20phosphinates%20and%20phosphine%20oxides%20and%20their%20unexpected%20cleavage%20under%20acidic%20conditions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22W.%22%2C%22lastName%22%3A%22Goldeman%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Grzegolec%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Blazejewska%22%7D%5D%2C%22abstractNote%22%3A%22The%20efficient%20synthesis%20of%20new%20imidazol-2-yl-%28amino%29methylphosphonic%20acids%2C%20phosphonates%20phosphinate%20esters%20and%20phosphine%20oxides%20is%20described.%20The%20synthetic%20methodology%20is%20based%20on%20nucleophilic%20addition%20of%20phosphorus%20species%20to%20imidazole-2%20derived%20imines.%20Additionally%2C%20it%20was%20discovered%20that%20heating%20the%20imidazol-2-yl-%28amino%29methylphosphonates%20with%20aqueous%20HCl%20or%20H%202SO%204%20leads%20to%20their%20decomposition%20resulting%20in%20a%20rupture%20of%20the%20C-P%20bond%2C%20elimination%20of%20the%20phosphorous-containing%20fragment%20and%20formation%20of%20the%20corresponding%20secondary%20imidazole-2%20alkylamines.%20A%20mechanistic%20pathway%20for%20the%20cleavage%20is%20postulated.%20%5Cu00a9%202011%20Elsevier%20Ltd.%20All%20rights%20reserved.%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.tet.2011.11.054%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A06Z%22%7D%7D%2C%7B%22key%22%3A%22K9CIIPSK%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Knapkiewicz%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BP.%20Knapkiewicz%2C%20K.%20Skowerski%2C%20D.%20E.%20Jask%26%23xF3%3Blska%2C%20M.%20Barbasiewicz%20and%20T.%20K.%20Olszewski%2C%20Nitration%20under%20continuous%20flow%20conditions%3A%20Convenient%20synthesis%20of%202-isopropoxy-5-nitrobenzaldehyde%2C%20an%20important%20building%20block%20in%20the%20preparation%20of%20nitro-substituted%20Hoveyda-Grubbs%20metathesis%20catalyst%2C%20%26lt%3Bi%26gt%3BOrganic%20Process%20Research%20and%20Development%26lt%3B%5C%2Fi%26gt%3B%2C%202012%2C%20%26lt%3Bb%26gt%3B16%26lt%3B%5C%2Fb%26gt%3B%2C%201430%26%23x2013%3B1435.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DK9CIIPSK%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Nitration%20under%20continuous%20flow%20conditions%3A%20Convenient%20synthesis%20of%202-isopropoxy-5-nitrobenzaldehyde%2C%20an%20important%20building%20block%20in%20the%20preparation%20of%20nitro-substituted%20Hoveyda-Grubbs%20metathesis%20catalyst%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Knapkiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Skowerski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.E.%22%2C%22lastName%22%3A%22Jask%5Cu00f3lska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Barbasiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22Herein%2C%20we%20describe%20the%20use%20of%20continuous%20flow%20chemistry%20for%20selective%2C%20efficient%20and%20reproducible%20nitration%20of%202-isopropoxybenzaldehyde%20to%20produce%20the%20desired%202-isopropoxy-5-nitrobenzaldehyde%2C%20an%20important%20building%20block%20in%20the%20preparation%20of%20a%20ligand%20of%20nitro-substituted%20Hoveyda-Grubbs%20metathesis%20catalyst.%20Nitration%20was%20done%20with%20red%20fuming%20HNO%203%2C%20and%20this%20challenging%20and%20hazardous%20process%20was%20performed%20using%20a%20flow-through%20silicon-glass%20microreactor%20equipped%20with%20a%20set%20of%20temperature%20sensors%2C%20and%20with%20a%20productivity%20of%2013%20g%5C%2Fh%2C%20providing%20us%20with%20a%20reproducible%20chemical%20process%20amenable%20for%20production%20of%20sufficient%20quantities%20of%202-isopropoxy-5-nitrobenzaldehyde%20for%20ongoing%20large-scale%20synthesis%20of%20nitro-substituted%20Hoveyda-Grubbs%20metathesis%20catalyst.%20%5Cu00a9%202012%20American%20Chemical%20Society.%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1021%5C%2Fop300116j%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A01Z%22%7D%7D%2C%7B%22key%22%3A%22MAHGDJYS%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20and%20Jask%5Cu00f3lska%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%20and%20D.%20E.%20Jask%26%23xF3%3Blska%2C%20Imidazol%28in%29ium-2-carboxylates%20as%20efficient%20precursors%20to%20N-heterocyclic%20carbene%20complexes%20of%20copper%20and%20silver%2C%20%26lt%3Bi%26gt%3BHeteroatom%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202012%2C%20%26lt%3Bb%26gt%3B23%26lt%3B%5C%2Fb%26gt%3B%2C%20605%26%23x2013%3B609.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DMAHGDJYS%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Imidazol%28in%29ium-2-carboxylates%20as%20efficient%20precursors%20to%20N-heterocyclic%20carbene%20complexes%20of%20copper%20and%20silver%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.E.%22%2C%22lastName%22%3A%22Jask%5Cu00f3lska%22%7D%5D%2C%22abstractNote%22%3A%22Copper%20and%20silver%20N-heterocyclic%20carbene%20%28NHC%29%20complexes%20were%20prepared%20through%20a%20simple%2C%20base-free%20protocol%20involving%20the%20decomposition%20of%20corresponding%20imidazol%28in%29ium-2-carboxylates%20under%20thermolytic%20conditions%20and%20a%20subsequent%20reaction%20of%20the%20in%20situ%20generated%20carbenes%20with%20copper%28I%29%20or%20silver%28I%29%20chloride%2C%20respectively.%20The%20desired%20NHC%20metal%20complexes%20were%20isolated%20with%20good%20yields%20after%20simple%20crystallization.%20%5Cu00a9%202012%20Wiley%20Periodicals%2C%20Inc.%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fhc.21056%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A25%3A57Z%22%7D%7D%2C%7B%22key%22%3A%22Y8U65PQI%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Knapkiewicz%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BP.%20Knapkiewicz%2C%20K.%20Skowerski%2C%20D.%20E.%20Jask%26%23xF3%3Blska%2C%20P.%20Kowalski%20and%20T.%20K.%20Olszewski%2C%20A%20flow-through%20silicon-glass%20microreactor%20for%20the%20synthesis%20of%202-isopropoxy-5-nitrobenzaldehyde%2C%20%26lt%3Bi%26gt%3BPrzeglad%20Elektrotechniczny%26lt%3B%5C%2Fi%26gt%3B%2C%202012%2C%20%26lt%3Bb%26gt%3B88%26lt%3B%5C%2Fb%26gt%3B%2C%2098%26%23x2013%3B100.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DY8U65PQI%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22A%20flow-through%20silicon-glass%20microreactor%20for%20the%20synthesis%20of%202-isopropoxy-5-nitrobenzaldehyde%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Knapkiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22K.%22%2C%22lastName%22%3A%22Skowerski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22D.E.%22%2C%22lastName%22%3A%22Jask%5Cu00f3lska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Kowalski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22Herein%20we%20describe%20a%20flow-through%20silicon-glass%20microreactor%20and%20its%20application%20in%20selective%20nitration%20of%202-isopropoxybenzaldehyde%20to%202-%20isopropoxy-5-nitrobenzaldehyde%2C%20important%20building%20block%20of%20nitro-substituted%20metathesis%20catalyst%20of%20type%20Hoveyda-Grubbs.%20The%20flow-through%20microreactor%20was%20fabricated%20using%20microengineering%20techniques%20from%20silicon%20and%20glass%2C%20materials%20resistant%20to%20nitration%20environment.%20Microreactor%20is%20equipped%20with%20miniature%20temperature%20sensors%20and%20with%20resistant%20to%20corrosion%20pressure%20sensors.%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%22%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A19%3A25Z%22%7D%7D%2C%7B%22key%22%3A%227FTW2VGA%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Knapkiewicz%20et%20al.%22%2C%22parsedDate%22%3A%222012%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BP.%20Knapkiewicz%2C%20K.%20Skowerski%2C%20D.%20E.%20Jask%5Cu00f3lska%2C%20P.%20Kowalski%20and%20T.%20K.%20Olszewski%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttp%3A%5C%2F%5C%2Fpe.org.pl%5C%2Fabstract_pl.php%3Fnid%3D6605%26%23039%3B%26gt%3BMikroreaktor%20krzemowo-szklany%20do%20syntezy%202-izopropoksy-5-%20nitrobenzaldehydu%20%5C%2F%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BPrzegl%5Cu0105d%20Elektrotechniczny.%26lt%3B%5C%2Fi%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D7FTW2VGA%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Mikroreaktor%20krzemowo-szklany%20do%20syntezy%202-izopropoksy-5-%20nitrobenzaldehydu%20%5C%2F%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pawe%5Cu0142%22%2C%22lastName%22%3A%22Knapkiewicz%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Krzysztof%22%2C%22lastName%22%3A%22Skowerski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Dagmara%20E.%22%2C%22lastName%22%3A%22Jask%5Cu00f3lska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Pawe%5Cu0142%22%2C%22lastName%22%3A%22Kowalski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222012%22%2C%22language%22%3A%22pol%22%2C%22DOI%22%3A%22%22%2C%22ISSN%22%3A%220033-2097%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fpe.org.pl%5C%2Fabstract_pl.php%3Fnid%3D6605%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-05-29T11%3A22%3A04Z%22%7D%7D%2C%7B%22key%22%3A%228HA2RUXQ%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20and%20Boduszek%22%2C%22parsedDate%22%3A%222011%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%20and%20B.%20Boduszek%2C%20Application%20of%20bis%28trimethylsilyl%29%20phosphonite%20in%20the%20efficient%20preparation%20of%20new%20heterocyclic%20-aminomethyl-%20H%20-phosphinic%20acids%2C%20%26lt%3Bi%26gt%3BSynthesis%26lt%3B%5C%2Fi%26gt%3B%2C%202011%2C%20437%26%23x2013%3B442.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3D8HA2RUXQ%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Application%20of%20bis%28trimethylsilyl%29%20phosphonite%20in%20the%20efficient%20preparation%20of%20new%20heterocyclic%20-aminomethyl-%20H%20-phosphinic%20acids%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%5D%2C%22abstractNote%22%3A%22A%20simple%2C%20reproducible%2C%20and%20efficient%20preparation%20of%20new%20heterocyclic%20-aminomethyl-H-phosphinic%20acids%20is%20reported.%20The%20synthetic%20protocol%20is%20based%20on%20the%20application%20of%20bis%28trimethylsilyl%29%20phosphonite%2C%20as%20an%20efficient%20phosphorous%20nucleophile%2C%20in%20the%20reaction%20with%20the%20corresponding%20heterocyclic%20imines.%20Subsequent%20methanolysis%20of%20the%20addition%20intermediates%20leads%20to%20the%20expected%20heterocyclic%20-aminomethyl-H-phosphinic%20acids%20in%20fair%20to%20good%20yields.%20Additionally%2C%20acidic%20hydrolysis%20of%20benzhydrylamino%20derivatives%20allows%20the%20efficient%20preparation%20of%20free%20-aminomethyl-H-phosphinic%20acids%20in%20good%20yields%20and%20high%20purity%20after%20simple%20crystallization.%20%5Cu00a9%20Georg%20Thieme%20Verlag%20Stuttgart%20New%20York.%22%2C%22date%22%3A%222011%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1055%5C%2Fs-0030-1258387%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A20Z%22%7D%7D%2C%7B%22key%22%3A%22N6GDGG2W%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Serra%20et%20al.%22%2C%22parsedDate%22%3A%222011%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BF.%20Serra%2C%20P.%20Coutrot%2C%20M.%20Est%26%23xE8%3Bve-Quelquejeu%2C%20P.%20Herson%2C%20T.%20K.%20Olszewski%20and%20C.%20Grison%2C%20Diastereoselective%20synthesis%20of%20lincosamine%20precursors%2C%20%26lt%3Bi%26gt%3BEuropean%20Journal%20of%20Organic%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202011%2C%201841%26%23x2013%3B1847.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DN6GDGG2W%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Diastereoselective%20synthesis%20of%20lincosamine%20precursors%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Serra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Coutrot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22M.%22%2C%22lastName%22%3A%22Est%5Cu00e8ve-Quelquejeu%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Herson%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22The%20stereoselective%20syntheses%20of%20the%20four%20aminodiol%20precursors%20of%20the%20diastereomers%20of%20lincosamine%20are%20reported.%20The%20procedure%20is%20based%20on%20the%20initial%20two-carbon%20elongationof%201%2C2%3B3%2C4-di-O-isopropylidene-%5Cu03b1-D-%20galactohexodialdo-1%2C5-pyranose%2C%20followed%20by%20the%20stereocontrolled%20introduction%20of%20the%20amino%20group%20by%20nucleophilic%20amination.%20Two%20complementary%20approaches%20have%20been%20investigated%20and%20compared%3A%20The%20first%20one%20is%20the%20direct%20transformation%20of%20%5Cu03b1-chloroglycidic%20ester%20into%20%5Cu03b2-amino-%5Cu03b1-keto%20ester.%20The%20second%20strategy%20is%20a%20three-step%20synthesis%20that%20is%20based%20on%20the%20treatment%20of%20the%20%5Cu03b2-iodo-%5Cu03b1-keto%20ester%20with%20dibenzylamine.%20Subsequent%20reduction%20of%20the%20%5Cu03b2-amino-%5Cu03b1-keto%20ester%20provides%20the%20pure%20D-erythro%2C%20L-threo%2C%20L-erythro%2C%20and%20D-threo%20aminodiols%20after%20chromatographic%20purification.%20Further%20classical%20transformations%20afford%20the%20N-acetyl%20derivatives%2C%20which%20are%20key%20precursors%20of%20the%20lincosamine%20diastereomers.%20Copyright%20%5Cu00a9%202011%20WILEY-VCH%20Verlag%20GmbH%20%26amp%3B%20Co.%20KGaA%2C%20Weinheim.%22%2C%22date%22%3A%222011%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fejoc.201001740%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A11Z%22%7D%7D%2C%7B%22key%22%3A%22G9HW88WG%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222011%22%2C%22numChildren%22%3A1%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20F.%20Serra%2C%20C.%20Grison%20and%20P.%20Herson%2C%20Efficient%20synthesis%20of%20direct%20precursors%20of%20the%20carbohydrate%20moiety%20of%20new%20antibacterials%206-epi-VIC-105555%20and%206-epi-VIC-II%2C%20%26lt%3Bi%26gt%3BJournal%20of%20Carbohydrate%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202011%2C%20%26lt%3Bb%26gt%3B30%26lt%3B%5C%2Fb%26gt%3B%2C%2094%26%23x2013%3B115.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DG9HW88WG%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Efficient%20synthesis%20of%20direct%20precursors%20of%20the%20carbohydrate%20moiety%20of%20new%20antibacterials%206-epi-VIC-105555%20and%206-epi-VIC-II%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22F.%22%2C%22lastName%22%3A%22Serra%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Herson%22%7D%5D%2C%22abstractNote%22%3A%22In%20search%20for%20new%20antibiotics%20we%20have%20developed%20a%20novel%20route%20leading%20to%20direct%20precursors%20of%20the%20carbohydrate%20moieties%20of%20new%20promising%20antibacterial%20agents%206-epi-VIC-105555%20and%206-epi-VIC-II.%20The%20presented%20synthetic%20strategy%20consists%20of%20using%20as%20starting%20material%20the%20readily%20available-dibenzylamino-%20ketoester%20and%20application%20of%20a%20sequence%20of%20chemical%20transformations%20on%20C-7%3A%20olefination%20or%20methylation%2C%20reduction%2C%20deoxygenation%20of%20the%20terminal%20alcohol%2C%20and%20finally%20hydrogenation.%20The%20desired%20molecules%20were%20obtained%20in%20a%20stereoselective%20fashion%20and%20with%20good%20overall%20yields.%20%5Cu00a9%20Taylor%20%26amp%3B%20Francis%20Group%2C%20LLC.%22%2C%22date%22%3A%222011%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1080%5C%2F07328303.2011.614982%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A15Z%22%7D%7D%2C%7B%22key%22%3A%22WW8YTNP4%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Michalska%20et%20al.%22%2C%22parsedDate%22%3A%222011%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BJ.%20Michalska%2C%20B.%20Boduszek%20and%20T.%20K.%20Olszewski%2C%20New%20quinoline-2%2C%20-3%2C%20and%204-yl-%28amino%29%20methylphosphonates%3A%20Synthesis%20and%20study%20on%20the%20C-P%20bond%20cleavage%20in%20quinoline-2%20and%20-4%20derivatives%20under%20acidic%20conditions%2C%20%26lt%3Bi%26gt%3BHeteroatom%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202011%2C%20%26lt%3Bb%26gt%3B22%26lt%3B%5C%2Fb%26gt%3B%2C%20617%26%23x2013%3B624.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DWW8YTNP4%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22New%20quinoline-2%2C%20-3%2C%20and%204-yl-%28amino%29%20methylphosphonates%3A%20Synthesis%20and%20study%20on%20the%20C-P%20bond%20cleavage%20in%20quinoline-2%20and%20-4%20derivatives%20under%20acidic%20conditions%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22J.%22%2C%22lastName%22%3A%22Michalska%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22B.%22%2C%22lastName%22%3A%22Boduszek%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%5D%2C%22abstractNote%22%3A%22Synthesis%20of%20new%20quinoline-%28amino%29methylphosphonic%20acids%2C%20their%20phosphonate%20esters%2C%20and%20phosphine%20oxides%20is%20presented.%20The%20desired%20new%20compounds%20were%20efficiently%20obtained%20by%20nucleophilic%20addition%20of%20phosphorous%20species%20to%20quinoline-derived%20Schiff%20bases.%20In%20addition%2C%20it%20was%20discovered%20that%20heating%20of%20quinolin-2%20and%20quinolin-4-yl-%28amino%29-methylphosphonates%20with%20aqueous%20HCl%20leads%20to%20their%20decomposition%20resulting%20in%20a%20rupture%20of%20the%20C-P%20bond%2C%20rejecting%20of%20the%20phosphorus%20containing%20fragment%2C%20and%20formation%20of%20the%20corresponding%20secondary%20quinoline-2%20and%20quinoline-4-alkylamines.%20Two%20alternative%20mechanistic%20pathways%20for%20this%20cleavage%20are%20postulated.%20Copyright%20%5Cu00a9%202011%20Wiley%20Periodicals%2C%20Inc.%22%2C%22date%22%3A%222011%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1002%5C%2Fhc.20704%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A25Z%22%7D%7D%2C%7B%22key%22%3A%22XTUMKU5Q%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222011%22%2C%22numChildren%22%3A0%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20C.%20Grison%2C%20C.%20Bomont%20and%20P.%20Coutrot%2C%20%26lt%3Ba%20class%3D%26%23039%3Bzp-ItemURL%26%23039%3B%20href%3D%26%23039%3Bhttp%3A%5C%2F%5C%2Fzoologie.umh.ac.be%5C%2Fasef%5C%2Fpdf%5C%2F2011_47_01_02%255Cfull%255COlszewski_et_al_2011_ASEF_47_1_2_045_054_full.pdf%26%23039%3B%26gt%3BSynthesis%20of%20insect%20pheromones%3A%20improved%20method%20for%20the%20preparation%20of%20queen%20substance%20and%20royal%20jelly%20of%20honeybees%20Apis%20mellifera%20%5C%2F%26lt%3B%5C%2Fa%26gt%3B%2C%20%26lt%3Bi%26gt%3BAnnales%20de%20la%20Societe%20Entomologique%20de%20France.%26lt%3B%5C%2Fi%26gt%3B%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DXTUMKU5Q%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Synthesis%20of%20insect%20pheromones%3A%20improved%20method%20for%20the%20preparation%20of%20queen%20substance%20and%20royal%20jelly%20of%20honeybees%20Apis%20mellifera%20%5C%2F%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Tomasz%20K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Claude%22%2C%22lastName%22%3A%22Grison%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Catherine%22%2C%22lastName%22%3A%22Bomont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22Philippe%22%2C%22lastName%22%3A%22Coutrot%22%7D%5D%2C%22abstractNote%22%3A%22%22%2C%22date%22%3A%222011%22%2C%22language%22%3A%22eng%22%2C%22DOI%22%3A%22%22%2C%22ISSN%22%3A%220037-9271%22%2C%22url%22%3A%22http%3A%5C%2F%5C%2Fzoologie.umh.ac.be%5C%2Fasef%5C%2Fpdf%5C%2F2011_47_01_02%255Cfull%255COlszewski_et_al_2011_ASEF_47_1_2_045_054_full.pdf%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-05-29T11%3A22%3A04Z%22%7D%7D%2C%7B%22key%22%3A%22VAANA89H%22%2C%22library%22%3A%7B%22id%22%3A415588%7D%2C%22meta%22%3A%7B%22creatorSummary%22%3A%22Olszewski%20et%20al.%22%2C%22parsedDate%22%3A%222010%22%2C%22numChildren%22%3A2%7D%2C%22bib%22%3A%22%26lt%3Bdiv%20class%3D%26quot%3Bcsl-bib-body%26quot%3B%20style%3D%26quot%3Bline-height%3A%201.35%3B%20%26quot%3B%26gt%3B%5Cn%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-entry%26quot%3B%20style%3D%26quot%3Bclear%3A%20left%3B%20%26quot%3B%26gt%3B%5Cn%20%20%20%20%26lt%3Bdiv%20class%3D%26quot%3Bcsl-left-margin%26quot%3B%20style%3D%26quot%3Bfloat%3A%20left%3B%20padding-right%3A%200.5em%3B%20text-align%3A%20right%3B%20width%3A%201em%3B%26quot%3B%26gt%3B1%26lt%3B%5C%2Fdiv%26gt%3B%26lt%3Bdiv%20class%3D%26quot%3Bcsl-right-inline%26quot%3B%20style%3D%26quot%3Bmargin%3A%200%20.4em%200%201.5em%3B%26quot%3B%26gt%3BT.%20K.%20Olszewski%2C%20C.%20Bomont%2C%20P.%20Coutrot%20and%20C.%20Grison%2C%20Lithiated%20anions%20derived%20from%20%28alkenyl%29pentamethyl%20phosphoric%20triamides%3A%20Useful%20synthons%20for%20the%20stereoselective%20synthesis%20of%209-oxo-%20and%2010-hydroxy-2%28E%29-decenoic%20acids%2C%20important%20components%20of%20queen%20substance%20and%20royal%20jelly%20of%20honeybee%20Apis%20mellifera%2C%20%26lt%3Bi%26gt%3BJournal%20of%20Organometallic%20Chemistry%26lt%3B%5C%2Fi%26gt%3B%2C%202010%2C%20%26lt%3Bb%26gt%3B695%26lt%3B%5C%2Fb%26gt%3B%2C%202354%26%23x2013%3B2358.%20%26lt%3Ba%20title%3D%26%23039%3BCite%20in%20RIS%20Format%26%23039%3B%20class%3D%26%23039%3Bzp-CiteRIS%26%23039%3B%20data-zp-cite%3D%26%23039%3Bapi_user_id%3D415588%26amp%3Bitem_key%3DVAANA89H%26%23039%3B%20href%3D%26%23039%3Bjavascript%3Avoid%280%29%3B%26%23039%3B%26gt%3BCite%26lt%3B%5C%2Fa%26gt%3B%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%20%20%26lt%3B%5C%2Fdiv%26gt%3B%5Cn%26lt%3B%5C%2Fdiv%26gt%3B%22%2C%22data%22%3A%7B%22itemType%22%3A%22journalArticle%22%2C%22title%22%3A%22Lithiated%20anions%20derived%20from%20%28alkenyl%29pentamethyl%20phosphoric%20triamides%3A%20Useful%20synthons%20for%20the%20stereoselective%20synthesis%20of%209-oxo-%20and%2010-hydroxy-2%28E%29-decenoic%20acids%2C%20important%20components%20of%20queen%20substance%20and%20royal%20jelly%20of%20honeybee%20Apis%20mellifera%22%2C%22creators%22%3A%5B%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22T.K.%22%2C%22lastName%22%3A%22Olszewski%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Bomont%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22P.%22%2C%22lastName%22%3A%22Coutrot%22%7D%2C%7B%22creatorType%22%3A%22author%22%2C%22firstName%22%3A%22C.%22%2C%22lastName%22%3A%22Grison%22%7D%5D%2C%22abstractNote%22%3A%22Lithiated%20anions%20derived%20from%20%28alkenyl%29pentamethyl%20phosphoric%20triamides%20as%20homoenolate%20equivalents%20are%20used%20in%20the%20reaction%20with%20halogenated%20acetal%20and%20ketal%20giving%20regioselectively%20the%20%5Cu03b3-alkylation%20adducts.%20Chemoselective%20acidic%20hydrolysis%20of%20the%20enephosphoramide%20moiety%20in%20the%20presence%20of%20acetal%20or%20ketal%20groups%20leads%20to%20expected%20carbonyl%20products%2C%20key%20intermediates%20in%20the%20synthesis%20of%20natural%20compounds.%20The%20synthetic%20potential%20of%20the%20presented%20strategy%20is%20illustrated%20by%20stereoselective%20synthesis%20of%20two%20pheromones%20namely%2C%209-oxo-2%28E%29-decenoic%20acid%201%20from%20queen%20substance%20and%2010-hydroxy-2%28E%29-decenoic%20acid%202%20from%20royal%20jelly%20of%20honeybee%20Apis%20mellifera.%20%5Cu00a9%202010%20Elsevier%20B.V.%22%2C%22date%22%3A%222010%22%2C%22language%22%3A%22%22%2C%22DOI%22%3A%2210.1016%5C%2Fj.jorganchem.2010.06.020%22%2C%22ISSN%22%3A%22%22%2C%22url%22%3A%22%22%2C%22collections%22%3A%5B%22624RWUWQ%22%5D%2C%22dateModified%22%3A%222020-06-06T05%3A26%3A42Z%22%7D%7D%5D%7D

J. Iwanejko, M. Sowiński, E. Wojaczyńska, T. K. Olszewski and M. Górecki, An approach to new chiral bicyclic imines and amines via Horner–Wadsworth–Emmons reaction, RSC Adv., 2020, 10, 14618–14629. Cite

C. Bihanic, K. Richards, T. K. Olszewski and C. Grison, Eco-Mn Ecocatalysts: Toolbox for Sustainable and Green Lewis Acid Catalysis and Oxidation Reactions, ChemCatChem, 2020, 12, 1529–1545. Cite

T. K. Olszewski, M. Bieniek and K. Skowerski, Ruthenium-Based Complexes Bearing Quaternary Ammonium Tags as Versatile Catalysts for Olefin Metathesis: From the Discovery to Practical Applications, Org. Process Res. Dev., 2020, 24, 125–145. Cite

E. Wolińska, K. Hałdys, J. Góra, T. K. Olszewski, B. Boduszek and R. Latajka, Phosphonic and Phosphinic Acid Derivatives as Novel Tyrosinase Inhibitors: Kinetic Studies and Molecular Docking, Chemistry and Biodiversity, , DOI:10.1002/cbdv.201900167. Cite

Ł. Gułajski, A. Tracz, K. Urbaniak, S. J. Czarnocki, M. Bieniek and T. K. Olszewski, Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation, Beilstein Journal of Organic Chemistry, 2019, 15, 160–166. Cite

J. Iwanejko, A. Brol, B. M. Szyja, M. Daszkiewicz, E. Wojaczyńska and T. K. Olszewski, Aminophosphonates and aminophosphonic acids with tetrasubstituted stereogenic center: Diastereoselective synthesis from cyclic ketimines, Organic and Biomolecular Chemistry, 2019, 17, 7352–7359. Cite

T. K. Olszewski, P. Adler and C. Grison, Bio-based catalysts from biomass issued after decontamination of effluents rich in copper— an innovative approach towards greener copper-based catalysis, Catalysts, , DOI:10.3390/catal9030214. Cite

J. Iwanejko, A. Brol, B. Szyja, M. Daszkiewicz, E. Wojaczyńska and T. K. Olszewski, Hydrophosphonylation of chiral hexahydroquinoxalin-2(1H)-one derivatives as an effective route to new bicyclic compounds: Aminophosphonates, enamines and imines, Tetrahedron, 2019, 75, 1431–1439. Cite

A. Stanovych, M. Balloy, T. K. Olszewski, E. Petit and C. Grison, Depollution of mining effluents: innovative mobilization of plant resources, Environmental Science and Pollution Research, 2019, 26, 19327–19334. Cite

C. De Laet, T. K. Olszewski and C. Grison, Melliferous potential of Mentha aquatica, Journal of Apicultural Research, 2019, 58, 714–719. Cite

E. Żymańczyk-Duda, N. Dunal, M. Brzezińska-Rodak, A. Osiewała, T. K. Olszewski, M. Klimek-Ochab and M. A. Serafin-Lewańczuk, First biological conversion of chiral heterophosphonate derivative - scaling and paths of conversion discussion /, Bioorganic Chemistry., , DOI:10.1016/j.bioorg.2019.01.047. Cite

A. Tracz, A. Gawin, M. Bieniek, T. K. Olszewski and K. Skowerski, Ammonium NHC-tagged olefin metathesis catalysts – influence of counter-ions on catalytic activity, New J. Chem., 2018, 42, 8609–8614. Cite

J. Iwanejko, E. Wojaczyńska and T. K. Olszewski, Green chemistry and catalysis in Mannich reaction, Current Opinion in Green and Sustainable Chemistry, 2018, 10, 27–34. Cite

N. Kmiecik, M. Serafin, E. Zymanczyk-Duda and T. K. Olszewski, Rapid enantiodifferentation of chiral organophosphorus compounds by 31P NMR spectroscopy in the presence of αcyclodextrin as the chiral solvating agent, Spectroscopy (Santa Monica), 2017, 32, 36–39 and 49. Cite

S. J. Czarnocki, I. Czeluśniak, T. K. Olszewski, M. Malinska, K. Woźniak and K. Grela, Rational and Then Serendipitous Formation of Aza Analogues of Hoveyda-Type Catalysts Containing a Chelating Ester Group Leading to a Polymerization Catalyst Family, ACS Catalysis, 2017, 7, 4115–4121. Cite

E. Proniewicz, S. Vantasin, T. K. Olszewski, B. Boduszek and Y. Ozaki, Biological application of water-based electrochemically synthesized CuO leaf-like arrays: SERS response modulated by the positional isomerism and interface type, Physical Chemistry Chemical Physics, 2017, 19, 31842–31855. Cite

E. Proniewicz, B. Gralec, T. K. Olszewski and B. Boduszek, Aqueous platinum nanoparticles solution for the detection of pyridine derivatives of aminophosphinic acid. Influence of positional isomerism, Applied Surface Science, 2017, 425, 941–947. Cite

N. Dunal, M. A. Serafin-Lewańczuk, T. K. Olszewski and E. Żymańczyk-Duda, Rapid enantiodifferentation of chiral organophosphorus compounds by 31P NMR spectroscopy in the presence of α-cyclodextrin as the chiral solvating agent /, Spectroscopy. Cite

G. Clavé, C. Garel, C. Poullain, B.-L. Renard, T. K. Olszewski, B. Lange, M. Shutcha, M.-P. Faucon and C. Grison, Ullmann reaction through ecocatalysis: Insights from bioresource and synthetic potential, RSC Advances, 2016, 6, 59550–59564. Cite

C. Grison, V. Escande and T. K. Olszewski, in Bioremediation and Bioeconomy, 2016, pp. 629–663. Cite

E. Pięta, E. Proniewicz, A. Kudelski, T. K. Olszewski and B. Boduszek, Vibrational characterization of α-aminophosphinic acid derivatives of pyridine: DFT, Raman and SERS spectroscopy studies, Vibrational Spectroscopy, 2016, 83, 115–125. Cite

B. Boduszek and T. K. Olszewski, Application of tris(trimethylsilyl) phosphite as a convenient phosphorus nucleophile in the direct synthesis of tetrasubstituted α-aminophosphonic acids from ketimines, Arkivoc, 2016, 2017, 173–179. Cite

E. Klem-Marciniak, T. K. Olszewski, K. Hoffmann, M. Huculak-Mączka and D. M. Popławski, Zastosowanie reakcji Mannicha do otrzymania chelatów nawozowych /, Proceedings of ECOpole., , DOI:10.2429/proc.2016.10(1)019. Cite

T. K. Olszewski, E. Wojaczyńska, R. Wieczorek and J. Bąkowicz, α-Hydroxyphosphonic acid derivatives of 2-azanorbornane: Synthesis, DFT calculations, and crystal structure analysis, Tetrahedron Asymmetry, 2015, 26, 601–607. Cite

T. K. Olszewski, Asymmetric synthesis of α-hydroxymethylphosphonates and phosphonic acids via hydrophosphonylation of aldehydes with chiral H-phosphonate, Tetrahedron Asymmetry, 2015, 26, 393–399. Cite

E. Pięta, E. Proniewicz, B. Boduszek, T. K. Olszewski, M. Nattich-Rak and Y. Kim, Probing the Ag, Au, and Cu electrode/pyridine-α-hydroxymethyl biphenyl phosphine oxide isomer interface with SERS, Applied Surface Science, 2015, 335, 167–183. Cite

V. Escande, T. K. Olszewski and C. Grison, From biodiversity to catalytic diversity: how to control the reaction mechanism by the nature of metallophytes, Environmental Science and Pollution Research, 2015, 22, 5653–5666. Cite

E. Wojaczyńska, J. Wojaczyński, K. Kleniewska, M. Dorsz and T. K. Olszewski, 2-Azanorbornane-a versatile chiral aza-Diels-Alder cycloadduct: Preparation, applications in stereoselective synthesis and biological activity, Organic and Biomolecular Chemistry, 2015, 13, 6116–6148. Cite

T. K. Olszewski and M. Majewski, Highly diastereoselective addition of chiral H-phosphonate to tert-butylsulfinyl aldimines: a convenient approach to (R)-α-aminophosphonic acids, Tetrahedron Asymmetry, 2015, 26, 846–852. Cite

E. Klem-Marciniak, T. K. Olszewski and M. Huculak-Mączka, in Nauka i przemysł - metody spektroskopowe w praktyce, nowe wyzwania i możliwości : praca zbiorowa. T. 1 / pod red. Zbigniewa Hubickiego.: Lublin : Uniwersytet Marii Curie-Skłodowskiej, 2015., 2015. Cite

E. Piȩta, E. Proniewicz, B. Boduszek, T. K. Olszewski, Y. Kim and L. M. Proniewicz, Exploring the isomer dependent SERS spectra of (diphenylphosphoryl) (pyridin-2, -3, and -4-yl)methanol adsorbed on gold nanocolloids, Journal of Spectroscopy, , DOI:10.1155/2014/894749. Cite

K. Skowerski, J. Białecki, A. Tracz and T. K. Olszewski, An attempt to provide an environmentally friendly solvent selection guide for olefin metathesis, Green Chemistry, 2014, 16, 1125–1130. Cite

E. Proniewicz, E. Pieta, K. Zborowski, A. Kudelski, B. Boduszek, T. K. Olszewski, Y. Kim and L. M. Proniewicz, Raman, surface-enhanced raman, and density functional theory characterization of (diphenylphosphoryl)(pyridin-2-, -3-, and -4-yl)methanol, Journal of Physical Chemistry A, 2014, 118, 5614–5625. Cite

V. Escande, T. K. Olszewski, E. Petit and C. Grison, Biosourced polymetallic catalysts: An efficient means to synthesize underexploited platform molecules from carbohydrates, ChemSusChem, 2014, 7, 1915–1923. Cite

V. Escande, T. K. Olszewski and C. Grison, Preparation of ecological catalysts derived from Zn hyperaccumulating plants and their catalytic activity in Diels-Alder reaction, Comptes Rendus Chimie, 2014, 17, 731–737. Cite

T. K. Olszewski, M. Figlus and M. Bieniek, Olefin metathesis: A versatile synthetic tool for use in preparation of active pharmaceutical ingredients, Chimica Oggi/Chemistry Today, 2014, 32, 22–29. Cite

T. K. Olszewski, Environmentally benign syntheses of α-substituted phosphonates: Preparation of α-amino- and α-hydroxyphosphonates in water, in ionic liquids, and under solvent-free conditions, Synthesis (Germany), 2014, 46, 403–429. Cite

K. Skowerski, P. Kasprzycki, M. Bieniek and T. K. Olszewski, Efficient, durable and reusable olefin metathesis catalysts with high affinity to silica gel, Tetrahedron, 2013, 69, 7408–7415. Cite

T. K. Olszewski, M. Bieniek, K. Skowerski and K. Grela, A new tool in the toolbox: Electron-withdrawing group activated -Ruthenium Catalysts for Olefin Metathesis, Synlett, , DOI:10.1055/s-0032-1318497. Cite

B. Boduszek, T. K. Olszewski, W. Goldeman, K. Grzegolec and P. Blazejewska, Preparation of new imidazol-2-yl-(amino)methylphosphonates, phosphinates and phosphine oxides and their unexpected cleavage under acidic conditions, Tetrahedron, 2012, 68, 1223–1229. Cite

P. Knapkiewicz, K. Skowerski, D. E. Jaskólska, M. Barbasiewicz and T. K. Olszewski, Nitration under continuous flow conditions: Convenient synthesis of 2-isopropoxy-5-nitrobenzaldehyde, an important building block in the preparation of nitro-substituted Hoveyda-Grubbs metathesis catalyst, Organic Process Research and Development, 2012, 16, 1430–1435. Cite

T. K. Olszewski and D. E. Jaskólska, Imidazol(in)ium-2-carboxylates as efficient precursors to N-heterocyclic carbene complexes of copper and silver, Heteroatom Chemistry, 2012, 23, 605–609. Cite

P. Knapkiewicz, K. Skowerski, D. E. Jaskólska, P. Kowalski and T. K. Olszewski, A flow-through silicon-glass microreactor for the synthesis of 2-isopropoxy-5-nitrobenzaldehyde, Przeglad Elektrotechniczny, 2012, 88, 98–100. Cite

P. Knapkiewicz, K. Skowerski, D. E. Jaskólska, P. Kowalski and T. K. Olszewski, Mikroreaktor krzemowo-szklany do syntezy 2-izopropoksy-5- nitrobenzaldehydu /, Przegląd Elektrotechniczny. Cite

T. K. Olszewski and B. Boduszek, Application of bis(trimethylsilyl) phosphonite in the efficient preparation of new heterocyclic -aminomethyl- H -phosphinic acids, Synthesis, 2011, 437–442. Cite

F. Serra, P. Coutrot, M. Estève-Quelquejeu, P. Herson, T. K. Olszewski and C. Grison, Diastereoselective synthesis of lincosamine precursors, European Journal of Organic Chemistry, 2011, 1841–1847. Cite

T. K. Olszewski, F. Serra, C. Grison and P. Herson, Efficient synthesis of direct precursors of the carbohydrate moiety of new antibacterials 6-epi-VIC-105555 and 6-epi-VIC-II, Journal of Carbohydrate Chemistry, 2011, 30, 94–115. Cite

J. Michalska, B. Boduszek and T. K. Olszewski, New quinoline-2, -3, and 4-yl-(amino) methylphosphonates: Synthesis and study on the C-P bond cleavage in quinoline-2 and -4 derivatives under acidic conditions, Heteroatom Chemistry, 2011, 22, 617–624. Cite

T. K. Olszewski, C. Grison, C. Bomont and P. Coutrot, Synthesis of insect pheromones: improved method for the preparation of queen substance and royal jelly of honeybees Apis mellifera /, Annales de la Societe Entomologique de France. Cite

T. K. Olszewski, C. Bomont, P. Coutrot and C. Grison, Lithiated anions derived from (alkenyl)pentamethyl phosphoric triamides: Useful synthons for the stereoselective synthesis of 9-oxo- and 10-hydroxy-2(E)-decenoic acids, important components of queen substance and royal jelly of honeybee Apis mellifera, Journal of Organometallic Chemistry, 2010, 695, 2354–2358. Cite

Search

Ph.D. D.Sc. Tomasz Olszewski

Scentific interests

Selected scientific articles

Professional career

Titles and degrees

Scientific internships

Awards

Pages

Latest news

Latest events

Meta